Central metal dependent modulation of induced-fit gas uptake in molecular porphyrin solids

The induced-fit accommodation of a variety of gaseous molecules including non-polar molecules has been demonstrated in porphyrin-based supramolecular architectures for the first time. Moreover, the gas uptake behaviour can be modulated by changing the central cation of porphyrin.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 54; no. 56; pp. 7822 - 7825
Main Authors Nishihara, Hirotomo, Ohwada, Mao, Kamimura, Takuya, Nishimura, Masato, Tanaka, Hideki, Hiraide, Shotaro, Miyahara, Minoru T, Ariga, Katsuhiko, Ji, Qingmin, Maruyama, Jun, Tani, Fumito
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 2018
Subjects
Molecular chains
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Summary:The induced-fit accommodation of a variety of gaseous molecules including non-polar molecules has been demonstrated in porphyrin-based supramolecular architectures for the first time. Moreover, the gas uptake behaviour can be modulated by changing the central cation of porphyrin.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc03646b