Expanded campestarene hosts for tetra- and dinuclear uranyl(vi) complexes

The first expanded campestarenes based on a keto-enamine scaffold have been constructed using uranyl acetate as a template. Macrocycles with six and eight aryl rings in their backbone host dinuclear and tetranuclear uranium(vi) species, respectively. The complexes were characterized by SCXRD, FT-IR,...

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Published inChemical communications (Cambridge, England) Vol. 54; no. 84; pp. 11869 - 11872
Main Authors Chaudhry, Mohammad T, Lelj, Francesco, MacLachlan, Mark J
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 28.10.2018
Subjects
Aromatic compounds
Crystallography
Fourier transforms
Infrared spectroscopy
NMR spectroscopy
Uranium
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Summary:The first expanded campestarenes based on a keto-enamine scaffold have been constructed using uranyl acetate as a template. Macrocycles with six and eight aryl rings in their backbone host dinuclear and tetranuclear uranium(vi) species, respectively. The complexes were characterized by SCXRD, FT-IR, UV-vis, and NMR spectroscopy, and DFT calculations corroborated their structures.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc07269h