Preparation of graphene-coated anodic alumina substrates for selective molecular transport

• Published in: Carbon Letters Vol. 30; no. 1; pp. 23 - 33
• Main Authors: Akhtar, Sultan, Ali, Sadaqat, Kafiah, Feras M., Ibrahim, Ahmed, Matin, Asif, Laoui, Tahar
• Format: Journal Article
• Language: English
• Published: Singapore Springer Singapore 01.02.2020; 한국탄소학회; Springer Nature B.V
• Subjects: Alumina; Aluminum; Aluminum oxide; Anodic coatings; Atomic force microscopy; Characterization and Evaluation of Materials; Chemical vapor deposition; Chemistry and Materials Science; Copper; Defects; Deionization; Desalination; Diffusion barriers; Diffusion cells; Electron microscopy; Experiments; Graphene; Ions; Materials Engineering; Materials Science; Membranes; Nanotechnology; Nylon 66; Original Article; Oxidation; Pore size; Potassium; Potassium chloride; Scanning electron microscopy; Spectrum analysis; Substrates; 자연과학일반; United States > US; Porous alumina; Ions transport; Nanopores; Graphene; Potassium chloride
• ISSN: 1976-4251; 2233-4998
• DOI: 10.1007/s42823-019-00066-4

In this paper, we report graphene composite membranes prepared by transfer of a layer of chemical vapor deposition graphene onto porous anodic alumina (AA) substrates with nominal pore size 20 and 30 nm, referred as 20AA and 30AA. The coated and uncoated substrates were characterized using optical and electron microscopy techniques. The bare substrates exhibited a smooth surfaces with a well-organized array of hexagonal pores, displaying an average pore size of 17 ± 3 (20AA) and 23 ± 3 nm (30AA). The scanning electron microscopy and atomic force microscopy analyses confirmed the successful transfer of graphene layer onto the target substrates. The molecular transport study was performed by introducing 0.5 M potassium chloride (KCl) and deionized water in a Side-bi-Side Franz diffusion cell. The graphene/20AA specimen blocked 66% ions transport, and graphene/30AA membrane about 64%. The ions blockage exceeded 90%, near the characteristics of defect-free graphene when the defects of the transferred graphene were sealed with Nylon 6,6. The results of this study suggest the potential use of graphene on AA substrates for water desalination and gas purification applications. Graphic abstract CVD graphene has shown > 90% blockage of KCl molecules when tested on porous alumina substrate (pore size ~ 20 nm).