Silver nanoparticles supported on polyethylene glycol/cellulose acetate ultrafiltration membranes: preparation and characterization of composite

• Published in: Cellulose (London) Vol. 24; no. 11; pp. 4997 - 5012
• Main Authors: Caloca, Jonathan, Flores-López, Lucía Z., Espinoza-Gomez, Heriberto, Sotelo-Barrera, Erika Lis, Núñez-Rivera, Alfredo, Cadena-Nava, Rubén Darío
• Format: Journal Article
• Language: English
• Published: Dordrecht Springer Netherlands 01.11.2017; Springer Nature B.V
• Subjects: Bacteria; Bioorganic Chemistry; Cellulose acetate; Ceramics; Chemical synthesis; Chemistry; Chemistry and Materials Science; Composites; Dispersion; E coli; Fourier transforms; Glass; Infrared spectroscopy; Membranes; Molecular composites; Morphology; Nanoparticles; Natural Materials; Organic Chemistry; Original Paper; Particulate composites; Permeability; Physical Chemistry; Polyethylene glycol; Polyethylenes; Polymer Sciences; Scanning electron microscopy; Silver; Spectroscopic analysis; Sustainable Development; Thermogravimetric analysis; Ultrafiltration; in situ composite membranes; ex situ composite membranes; Ag-NPs/PEG/CA UF composite membranes; Silver nanoparticles; Silver nanoparticles supported
• ISSN: 0969-0239; 1572-882X
• DOI: 10.1007/s10570-017-1471-y

In this research work, silver nanoparticles/polyethylene glycol/cellulose acetate ultrafiltration (Ag-NPs/PEG/CA UF) composite membranes were synthesized and characterized. The Ag-NPs were embedded in the polymer matrix by two methods: in situ and ex situ; varying the type of solvent used (dimethylformamide, DMF; or N -methyl-2-pyrrolidone, NMP). The Ag-NPs used in the ex situ method were synthesized by a green chemistry reduction method. The composite membranes were characterized by Fourier transform infrared spectroscopy with attenuated total reflection (FTIR-ATR), scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS), and thermogravimetric analysis-derivative thermogravimetric analysis (TGA-DTG); the molecular weight cut-off and permeability were also determined. Moreover, the antibacterial efficiency of the composite membranes was measured against bacteria like Escherichia coli and Staphylococcus aureus . By FTIR-ATR analysis it was possible to observe that the Ag-NPs embedded in membranes changed the membrane morphology. The SEM-EDS analysis showed that the in situ composite membranes have good dispersity of Ag-NPs, DMF FB being the most densely populated obtained. By another hand, the ex situ DMF NP composite membrane presented the highest amount of silver signals per unit area (µm 2 ). The permeability of the membrane was affected by the presence of the Ag-NPs; the DMF NP composite membrane had the highest permeate flow, while DMF FB had the highest antibacterial activity.