High efficiency and stability of Au-Cu/hydroxyapatite catalyst for the oxidation of carbon monoxide

• Published in: RSC advances Vol. 7; no. 72; pp. 4542 - 45431
• Main Authors: Guo, Jiuli, Yu, Huanhuan, Dong, Feng, Zhu, Baolin, Huang, Weiping, Zhang, Shoumin
• Format: Journal Article
• Language: English
• Published: 01.01.2017
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/c7ra08781k

A highly efficient and stable Au-Cu/hydroxyapatite (HAP, Ca 10 (PO 4 ) 6 (OH) 2 ) catalyst was reported. HAP was prepared through a deposition-precipitation method. Au-Cu/HAP catalysts were obtained by a two-step impregnation approach. The samples were characterized by XRD, TEM, SEM, UV-Vis, ICP, XPS, H 2 -TPR, and O 2 -TPD. CO oxidation reaction was carried out to evaluate the catalytic performance of samples. TEM and UV-Vis results showed that the metallic particles supported on Au-Cu/HAP were smaller than those on Au/HAP, and they were highly dispersed on the HAP support. Patterns of XPS revealed that CuO nanoparticles were formed in the Cu/HAP catalyst, while CuO and Cu 2 O species coexisted in Au-Cu/HAP catalyst. Based on the O 2 -TPD data, the addition of copper to Au/HAP gave rise to more new O 2 adsorption sites and bigger O 2 adsorption capacity. The catalysis results indicated that the Au-Cu/HAP was capable of obtaining higher efficiency and stability compared with Au/HAP and Cu/HAP for CO oxidation. It was likely that the synergistic interaction between gold and CuO x phase created the most active sites on Au-Cu/HAP and was responsible for the enhanced activity and stability in comparison with Au/HAP and Cu/HAP. Synergistic effect between gold and CuO x phase for high efficiency and stability.