Octameric and Decameric Aluminophosphates

Big Al: The title compounds are not only among the largest molecular aluminophosphates synthesized thus far, but are also rare polyhedral cages that contain AlO4, AlO5, and AlO6 coordination geometries (see structure; red O, blue Al, pink P). The cores of these aluminophosphates represent new struct...

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Published inAngewandte Chemie International Edition Vol. 45; no. 42; pp. 7022 - 7026
Main Authors Murugavel, Ramaswamy, Kuppuswamy, Subramaniam
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 27.10.2006
WILEY‐VCH Verlag
Subjects
aluminum
cluster compounds
phosphates
structure elucidation
zeolite analogues
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Summary:Big Al: The title compounds are not only among the largest molecular aluminophosphates synthesized thus far, but are also rare polyhedral cages that contain AlO4, AlO5, and AlO6 coordination geometries (see structure; red O, blue Al, pink P). The cores of these aluminophosphates represent new structural building units (SBUs) in zeolite chemistry.
Bibliography:ark:/67375/WNG-PCP5J8XD-8
This work was supported by DST, New Delhi, in the form of a Swarnajayanti Fellowship to R.M. We thank the National Single Crystal X-ray Diffractometer Facility and SAIF (IIT-Bombay) for the diffraction and spectroscopic data, respectively.
DST
ArticleID:ANIE200601979
istex:A36AD05088DA7CCE6250BFCE5179CD6FE50C5CF3
This work was supported by DST, New Delhi, in the form of a Swarnajayanti Fellowship to R.M. We thank the National Single Crystal X‐ray Diffractometer Facility and SAIF (IIT‐Bombay) for the diffraction and spectroscopic data, respectively.
ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200601979