Significant Promotion of Morphology in Fabricating Efficient Environment Protector

A new strategy of morphology control was applied for mesoporous silica SBA-15 to fabricate efficient envi- ronment protector, and the micro- and macro-morphology of SBA-15 were simultaneously controlled in weak acidic condition by using citric acid. Through simply tuning the synthetic temperature, m...

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Published inChinese journal of chemistry Vol. 30; no. 9; pp. 2073 - 2078
Main Author 周瑜 钱文娟 杨菁 周仕禄 王英 朱建华
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.09.2012
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
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Online AccessGet full text
ISSN1001-604X
1614-7065
DOI10.1002/cjoc.201200558

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Summary:A new strategy of morphology control was applied for mesoporous silica SBA-15 to fabricate efficient envi- ronment protector, and the micro- and macro-morphology of SBA-15 were simultaneously controlled in weak acidic condition by using citric acid. Through simply tuning the synthetic temperature, monolithic SBA-15 materi- als with tunable macroporous structure was fabricated by using mild shearing force field in the citric acid route. Owning to the strong promotion of special morphology, the SBA-15 monolith can efficiently eliminate the phenol from environmental tobacco smoke (ETS), and the reduction ratio is twice higher than that by tetraethylenepen- tamine (TEPA) modified powder-like SBA-15. These results indicated that morphology of mesoporous materials played a dominant role in environmental purification.
Bibliography:31-1547/O6
A new strategy of morphology control was applied for mesoporous silica SBA-15 to fabricate efficient envi- ronment protector, and the micro- and macro-morphology of SBA-15 were simultaneously controlled in weak acidic condition by using citric acid. Through simply tuning the synthetic temperature, monolithic SBA-15 materi- als with tunable macroporous structure was fabricated by using mild shearing force field in the citric acid route. Owning to the strong promotion of special morphology, the SBA-15 monolith can efficiently eliminate the phenol from environmental tobacco smoke (ETS), and the reduction ratio is twice higher than that by tetraethylenepen- tamine (TEPA) modified powder-like SBA-15. These results indicated that morphology of mesoporous materials played a dominant role in environmental purification.
mesoporous materials, SBA-15, morphology control, surface modification, environmental protection
Zhou, yu Qian, Wenjuan Yang, Jing Zhou, Shilub Wang, Ying Zhu, Jianhua(a Key Laboratory of Mesoscopic Chemistry of MOE, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China b Technology Centre of Etsong Tobacco Group, Qingdao, Shandong 266021, China c Ecomaterials and Renewable Energy Research Center (ERERC), Nanjing University, Nanjing, Jiangsu 210093, China)
863 Program of the MST of China - No. 2008AA06Z327
ark:/67375/WNG-48S0LJFH-Z
NSF of China - No. 21173117 and 20873059
ArticleID:CJOC201200558
the Scientific Research Foundation of Graduate School, and Analysis Center of Nanjing University
istex:0CEEB764C83AE8E638F0C6277947DB6BA70335C3
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201200558