A Novel Metal-free Reductive Esterification of N-Tosylhydrazones with Carboxylic Acids

A novel method for the synthesis of esters via reductive coupling of N-tosylhydrazones with carboxylic acids under metal-free conditions has been developed. Various functional groups were found to be tolerable under the re- action conditions to afford low to good yields.

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Bibliographic Details
Published inChinese journal of chemistry Vol. 30; no. 8; pp. 1862 - 1866
Main Author 周安坤 吴磊 李大志 陈庆庆 张晓 夏吾炯
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.08.2012
WILEY‐VCH Verlag
Wiley
Wiley Subscription Services, Inc
Subjects
Acids
Carboxylic acids
Chemistry
Chemistry, Multidisciplinary
esterification
Esters
metal-free
N-tosylhydrazones
Physical Sciences
Science & Technology
官能团
羧酸
还原偶联
酯化反应
金属条
esterification
metal-free
N-tosylhydrazones
carboxylic acids
Online AccessGet full text
ISSN1001-604X
1614-7065
DOI10.1002/cjoc.201200387

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Summary:A novel method for the synthesis of esters via reductive coupling of N-tosylhydrazones with carboxylic acids under metal-free conditions has been developed. Various functional groups were found to be tolerable under the re- action conditions to afford low to good yields.
Bibliography:31-1547/O6
Zhou Ankun,Wu Lei, Li Dazhi, Chen Qingqing,Zhang Xiao,Xia Wujiong（ State Key Lab of Urban Water Resource and Environment, the Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin, Heilongjiang 150080, China）
metal-free, N-tosylhydrazones, esterification, carboxylic acids
A novel method for the synthesis of esters via reductive coupling of N-tosylhydrazones with carboxylic acids under metal-free conditions has been developed. Various functional groups were found to be tolerable under the re- action conditions to afford low to good yields.
the China Postdoctoral Science Foundation - No. 2011M500096
Harbin Institute of Technology
ArticleID:CJOC201200387
ark:/67375/WNG-LMKNK04W-8
istex:E96386DE4DCD2EECF1504CA0196454F104EF7792
Natural Scientific Research Innovation Foundation in Harbin Institute of Technology - No. HIT.NSRIF 2010054
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201200387