2,2′:6′,2′′:6′′,6-Trioxytriphenylamine: Synthesis and Properties of the Radical Cation and Neutral Species
A flat radical: Oxygen‐bridged triphenylamine 1 and its radical cation 2 were prepared. The neutral compound has a shallow bowl structure, whereas the radical cation is planar. The properties of the highly stable radical cation were clarified; such compounds have potential applicability in electroni...
Saved in:
Published in | Angewandte Chemie (International ed.) Vol. 44; no. 26; pp. 4056 - 4058 |
---|---|
Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag
27.06.2005
WILEY‐VCH Verlag Wiley |
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | A flat radical: Oxygen‐bridged triphenylamine 1 and its radical cation 2 were prepared. The neutral compound has a shallow bowl structure, whereas the radical cation is planar. The properties of the highly stable radical cation were clarified; such compounds have potential applicability in electronic and magnetic materials. |
---|---|
Bibliography: | ArticleID:ANIE200500397 istex:C15E8585CBB37427E086AE384E36FCDFDC294CE3 ark:/67375/WNG-3XMKV7N6-8 This work was partially supported by a research fund from Chisso Corporation, Japan. We thank Professor Stephen F. Nelsen for valuable discussions. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.200500397 |