Robust CoAl Alloy： Highly Active, Reusable and Green Catalyst in the Hydrogenolysis of Glycerol

CoAl alloy catalyst is found, for the first time, to be highly active, selective and reusable for the synthesis of diols via the hydrogenolysis of glycerol under mild conditions. The products and the catalyst could be self-separated from the reaction system through a simple reactor.

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Bibliographic Details
Published inChinese journal of chemistry Vol. 29; no. 8; pp. 1563 - 15662
Main Author 郭晓洋 尹安远 郭晓东 郭秀英 戴维林 范康年
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.08.2011
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
1,2‐propanediol
2-propanediol
biomass
CoAl
Glycerol
hydrogenolysis
反应体系
可重复使用
合金催化剂
氢解
煤炭
甘油
醇合成
高活性
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Summary:CoAl alloy catalyst is found, for the first time, to be highly active, selective and reusable for the synthesis of diols via the hydrogenolysis of glycerol under mild conditions. The products and the catalyst could be self-separated from the reaction system through a simple reactor.
Bibliography:31-1547/O6
Guo, Xiaoyanga Guo, Xiuying Yin, Anyuana Dai, Weilin Guo, Xiaodon Fan, Kangnian（ a Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China b State Key Laboratory of High Field Laser Physics, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China）
CoAl alloy catalyst is found, for the first time, to be highly active, selective and reusable for the synthesis of diols via the hydrogenolysis of glycerol under mild conditions. The products and the catalyst could be self-separated from the reaction system through a simple reactor.
CoAl, biomass, glycerol, hydrogenolysis, 1,2-propanediol
the Research Fund for the Doctoral Program of Higher Education - No. 20090071110011
the National Natural Science Foundation of China - No. 20973042
the Major State Basic Resource Development Program - No. 2003CB 615807
istex:A6309A961523FD115D05BA27944EAC8A6BFD8ACA
ArticleID:CJOC201180281
ark:/67375/WNG-CK426KCN-G
the Science & Technology Commission of Shanghai Municipality - No. 08DZ2270500
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201180281