Molybdenum carbide in-situ embedded into carbon nanosheets as efficient bifunctional electrocatalysts for overall water splitting

• Published in: Electrochimica acta Vol. 298; pp. 305 - 312
• Main Authors: Xing, Jiangnan, Li, Yang, Guo, Siwei, Jin, Ting, Li, Haixia, Wang, Yijing, Jiao, Lifang
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01.03.2019; Elsevier BV
• Subjects: Beta phase; Bifunctional; Biological materials; Carbon; Electrocatalysis; Electrocatalysts; Hydrogen evolution reactions; Molybdenum; Molybdenum carbide; Nanosheets; Overall water splitting; Oxygen evolution reactions; Porosity; Synergistic effect; Water splitting; Electrocatalysis; Bifunctional; Molybdenum carbide; Overall water splitting; Biological materials
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2018.12.091

Developing low-cost and highly efficient electrocatalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is attractive for overall water splitting. Herein, we firstly use the globally generated green cornstalks as the carbon source to prepare highly efficient bifunctional pure β-phase molybdenum carbide (β-Mo2C) electrocatalysts. Due to the highly intrinsic activity of β-Mo2C, high porosity of the resultant and synergistic effect between the Mo2C and carbon matrix, the as-prepared catalyst exhibits excellent electrocatalytic activities with low overpotentials of 130 mV and 274 mV to achieve a current density of 10 mA cm−2 for the HER and OER, respectively. As a bifunctional electrocatalyst for overall water splitting, the electrolyzer only needs a cell voltage of 1.65 V at 10 mA cm−2 in alkaline water, as well as long-term stability of 30 h. This intriguing preparation strategy will open up an exciting new avenue for the synthesis of other carbides.