The growth and characterization of GaN films on cone-shaped patterned sapphire by MOCVD
GaN films are grown on cone-shaped patterned sapphire substrates (CPSSs) by metal-organic chemical vapor deposition, and the influence of the temperature during the middle stage of GaN growth on the threading dislocation (TD) density of GaN is investigated. High-resolution X-ray diffraction (XRD) an...
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Published in | Journal of semiconductors Vol. 34; no. 11; pp. 20 - 24 |
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Format | Journal Article |
Language | English |
Published |
01.11.2013
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ISSN | 1674-4926 |
DOI | 10.1088/1674-4926/34/11/113002 |
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Abstract | GaN films are grown on cone-shaped patterned sapphire substrates (CPSSs) by metal-organic chemical vapor deposition, and the influence of the temperature during the middle stage of GaN growth on the threading dislocation (TD) density of GaN is investigated. High-resolution X-ray diffraction (XRD) and cathodeluminescence (CL) were used to characterize the GaN films. The XRD results showed that the edge-type dislocation density of GaN grown on CPSS is remarkably reduced compared to that of GaN grown on conventional sapphire substrates (CSSs). Furthermore, when the growth temperature in the middle stage of GaN grown on CPSS decreases, the full width at half maximum of the asymmetry (102) plane of GaN is reduced. This reduction is attributed to the enhancement of vertical growth in the middle stage with a more triangular-like shape and the bending of TDs. The CL intensity spatial mapping results also showed the superior optical properties of GaN grown on CPSS to those of GaN on CSS, and that the density of dark spots of GaN grown on CPSS induced by nonradiative recombination is reduced when the growth temperature in the middle stage decreases. |
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AbstractList | GaN films are grown on cone-shaped patterned sapphire substrates (CPSSs) by metal-organic chemical vapor deposition, and the influence of the temperature during the middle stage of GaN growth on the threading dislocation (TD) density of GaN is investigated. High-resolution X-ray diffraction (XRD) and cathodeluminescence (CL) were used to characterize the GaN films. The XRD results showed that the edge-type dislocation density of GaN grown on CPSS is remarkably reduced compared to that of GaN grown on conventional sapphire substrates (CSSs). Furthermore, when the growth temperature in the middle stage of GaN grown on CPSS decreases, the full width at half maximum of the asymmetry (102) plane of GaN is reduced. This reduction is attributed to the enhancement of vertical growth in the middle stage with a more triangular-like shape and the bending of TDs. The CL intensity spatial mapping results also showed the superior optical properties of GaN grown on CPSS to those of GaN on CSS, and that the density of dark spots of GaN grown on CPSS induced by nonradiative recombination is reduced when the growth temperature in the middle stage decreases. GaN films are grown on cone-shaped patterned sapphire substrates (CPSSs) by metal-organic chemical vapor deposition, and the influence of the temperature during the middle stage of GaN growth on the threading dislocation (TD) density of GaN is investigated. High-resolution X-ray diffraction (XRD) and cathode-luminescence (CL) were used to characterize the GaN films. The XRD results showed that the edge-type dislocation density of GaN grown on CPSS is remarkably reduced compared to that of GaN grown on conventional sapphire substrates (CSSs). Furthermore, when the growth temperature in the middle stage of GaN grown on CPSS decreases, the full width at half maximum of the asymmetry (102) plane of GaN is reduced. This reduction is attributed to the enhancement of vertical growth in the middle stage with a more triangular-like shape and the bending of TDs. The CL intensity spatial mapping results also showed the superior optical properties of GaN grown on CPSS to those of GaN on CSS, and that the density of dark spots of GaN grown on CPSS induced by nonradiative recombination is reduced when the growth temperature in the middle stage decreases. |
Author | 井亮 肖红领 王晓亮 王翠梅 邓庆文 李志东 丁杰钦 王占国 侯洵 |
AuthorAffiliation | Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences,Beijing 100083, China Beijing Key Laboratory of Low Dimensional Semiconductor Materials and Devices, Beijing 100083, China ISCAS-XJTU Joint Laboratory of Functional Materials and Devices for lnformatics, Beijing 100083, China Xi'an Jiaotong University, Xi'an 710049, China |
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Cites_doi | 10.1143/JJAP.37.L1195 10.1016/S0022-0248(96)00620-3 10.1088/1674-1056/20/2/028402 10.1063/1.120044 10.1143/JJAP.34.L1184 10.1016/j.sse.2009.11.005 10.1038/386351a0 10.1063/1.2830981 10.1016/0022-0248(94)90448-0 10.1103/PhysRevLett.79.3672 10.1063/1.3388014 10.1016/S0022-0248(00)00707-7 10.1016/j.physb.2009.08.318 10.1016/j.sse.2005.06.022 10.1016/j.jcrysgro.2004.08.070 10.1109/LPT.2011.2160051 10.1063/1.366235 10.1143/JJAP.40.L583 10.1109/TED.2009.2034495 |
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Notes | GaN; threading dislocation; patterned sapphire substrate; metal-organic chemical vapor deposition GaN films are grown on cone-shaped patterned sapphire substrates (CPSSs) by metal-organic chemical vapor deposition, and the influence of the temperature during the middle stage of GaN growth on the threading dislocation (TD) density of GaN is investigated. High-resolution X-ray diffraction (XRD) and cathodeluminescence (CL) were used to characterize the GaN films. The XRD results showed that the edge-type dislocation density of GaN grown on CPSS is remarkably reduced compared to that of GaN grown on conventional sapphire substrates (CSSs). Furthermore, when the growth temperature in the middle stage of GaN grown on CPSS decreases, the full width at half maximum of the asymmetry (102) plane of GaN is reduced. This reduction is attributed to the enhancement of vertical growth in the middle stage with a more triangular-like shape and the bending of TDs. The CL intensity spatial mapping results also showed the superior optical properties of GaN grown on CPSS to those of GaN on CSS, and that the density of dark spots of GaN grown on CPSS induced by nonradiative recombination is reduced when the growth temperature in the middle stage decreases. 11-5781/TN Jing Liang, Xiao Hongling, Wang Xiaoliang, Wang Cuimei, Deng Qingwen, Li Zhidong, Ding Jieqin, Wang Zhanguo, and Hou Xun( 1 Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences Beijing 100083, China 2Beijing Key Laboratory of Low Dimensional Semiconductor Materials and Devices, Beijing 100083, China 3 ISCAS-XJTU Joint Laboratory of Functional Materials and Devices for lnformatics, Beijing 100083, China 4Xi'an Jiaotong University, Xi'an 710049, China) ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
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References | 11 13 14 15 Rorma P T (12) 2009; 404 16 17 18 19 Zhang Xiaobin (3) 2011; 20 1 2 4 5 6 7 8 9 Kazumasa H (20) 2001; 13 10 |
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SubjectTerms | Chemical vapor deposition Density Diffraction Gallium nitrides GaN薄膜 MOCVD生长 Reduction Sapphire Semiconductors X-ray diffraction X-射线衍射 图案化 蓝宝石衬底 表征 金属有机物化学气相沉积 锥形 |
Title | The growth and characterization of GaN films on cone-shaped patterned sapphire by MOCVD |
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