Fabrication of a novel PbO2 electrode with a graphene nanosheet interlayer for electrochemical oxidation of 2-chlorophenol

• Published in: Electrochimica acta Vol. 240; pp. 424 - 436
• Main Authors: Duan, Xiaoyue, Zhao, Cuimei, Liu, Wei, Zhao, Xuesong, Chang, Limin
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 20.06.2017; Elsevier BV
• Subjects: 2-Chlorophenol; Accelerated life tests; Accelerated tests; Aromatic compounds; Catechol; Chlorophenol; Crystal structure; Degradation; Electrochemical analysis; Electrochemical impedance spectroscopy; Electrochemical oxidation; Electrodes; Electrophoretic deposition; Graphene; Graphene nanosheet; Interlayer; Interlayers; Lead oxides; Maleic acid; Microcrystals; Nanosheets; Oxidation; PbO2 electrode; Photoelectron spectroscopy; Quinones; Radicals; Scanning electron microscopy; Transmission electron microscopy; X-ray diffraction; Interlayer; Graphene nanosheet; PbO2 electrode; Electrochemical oxidation; 2-Chlorophenol
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2017.04.114

•A novel PbO2 electrode with a GNS interlayer (GSN-PbO2) was prepared.•The GNS interlayer reduced grain size of β-PbO2 crystals.•The GNS interlayer enhanced electrochemical activity of PbO2 electrode.•The lifetime of GSN-PbO2 electrode was 1.93 times that of PbO2 electrode.•An electrochemical mineralization mechanism of 2-chlorophenol was proposed. A novel PbO2 electrode with a graphene nanosheet interlayer (marked as GNS-PbO2) was prepared combining electrophoretic deposition and electro-deposition technologies. The micro morphology, crystal structure and surface chemical states of GNS-PbO2 electrodes were characterized using scanning electronic microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Their electrochemical properties and stability were determined using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), ·OH radicals test and accelerated life test, and compared with traditional PbO2 electrodes. Besides, their potential application in the electrochemical degradation of 2-chlorophenol (2-CP) was investigated. The GNS-PbO2 electrode possessed perfect octahedral β-PbO2 microcrystals, and its grain size was much smaller than that of traditional PbO2 electrode. It exhibited higher electrochemical activity than traditional PbO2 electrode due to its larger electrochemical active surface area and stronger ·OH radicals generation ability. The service lifetime of GNS-PbO2 electrode (107.9h) was 1.93 times longer than that of traditional PbO2 electrode (55.9h). The electrochemical degradation rate constant of 2-CP on GNS-PbO2 electrode (kapp=2.75×10−2min−1) is much higher than for PbO2 electrode (kapp=1.76×10−2min−1). 2-CP oxidation yielded intermediates including aromatic compounds (catechol, phenol and ortho-benzoquinone) and organic acids (oxalic acid, maleic acid and glutaconic acid), and a possible degradation pathway for 2-CP was proposed accordingly.