Molecular imprinting polymer with polyoxometalate/carbon nitride nanotubes for electrochemical recognition of bilirubin

• Published in: Electrochimica acta Vol. 246; pp. 135 - 140
• Main Authors: Yola, Mehmet Lütfi, Göde, Ceren, Atar, Necip
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 20.08.2017; Elsevier BV
• Subjects: Bilirubin; Blood plasma; Carbon nitride; Carbon nitride nanotubes; Chemical compounds; Energy transmission; Linearity; Molecular imprinting; Nanocomposites; Nanotubes; Polyoxometalate; Polyoxometallates; Selectivity; Sensors; Studies; Transmission electron microscopy; Voltammetry; X ray analysis; X ray photoelectron spectroscopy; Polyoxometalate; Carbon nitride nanotubes; Bilirubin; Molecular imprinting
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2017.06.053

•Bilirubin-imprinted sensor is developed for the sensitive detection of bilirubin•The prepared based on nanocomposite were characterized by several methods.•Bilirubin-imprinted sensor offers the important advantages•Bilirubin-imprinted sensor is preferred to the other methods for analysis In this work, a new molecular imprinted sensor based on polyoxometalate (H3PW12O40, POM) functionalized carbon nitride nanotubes (C3N4 NTs) nanocomposite was prepared for bilirubin (BR) analysis. The structures of prepared surfaces based on the nanocomposite were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), x-ray photoelectron spectroscopy (XPS) and energy dispersive x-ray analysis (EDX). After that, BR imprinted electrode on H3PW12O40/C3N4 NTs nanocomposite was developed by cyclic voltammetry (CV) in 100mM pyrrole containing 25mM BR. The linearity range and the detection limit of the developed method were calculated as 1.0×10−12–1.0×10−10M and 3.0×10−13M, respectively. In addition, the imprinted sensor was applied to human plasma samples with high recovery and selectivity.