Nickel-Containing Perovskites, PrNi0.4Fe0.6O3–δ and PrNi0.4Co0.6O3–δ, as Potential Electrodes for Protonic Ceramic Electrochemical Cells

• Published in: Materials Vol. 15; no. 6; p. 2166
• Main Authors: Tarutin, Artem, Kasyanova, Anna, Vdovin, Gennady, Lyagaeva, Julia, Medvedev, Dmitry
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 15.03.2022; MDPI
• Subjects: Ceramics; Chemical compatibility; Chemical energy; Climate change; compatibility; Composite materials; Cooling; EIS; Electrical resistivity; Electrochemical analysis; Electrochemical cells; Electrode polarization; Electrodes; Electrolytes; Electrolytic cells; Fuel cells; Functional materials; Hydrogen; Iron; Nickel; Nitrates; PCFCs; Perovskites; PrNiO3; Software; Thermal expansion; Transport properties; Italy; Germany
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma15062166

Protonic ceramic fuel cells (PCFCs) offer a convenient means of converting chemical energy into electricity with high performance and efficiency at low- and intermediate-temperature ranges. However, in order to ensure good life-time stability of PCFCs, it is necessary to ensure rational chemical design in functional materials. Within the present work, we propose new Ni-based perovskite phases of PrNi0.4M0.6O3–δ (where M = Co, Fe) for potential utilization in protonic ceramic electrochemical cells. Along with their successful synthesis, functional properties of the PrNi0.4M0.6O3–δ materials, such as chemical compatibility with a number of oxygen-ionic and proton-conducting electrolytes, thermal expansion behavior, electrical conductivity, and electrochemical behavior, were comprehensively studied. According to the obtained data, the Co-containing nickelate exhibits excellent conductivity and polarization behavior; on the other hand, it demonstrates a high reactivity with all studied electrolytes along with elevated thermal expansion coefficients. Conversely, while the iron-based nickelate had superior chemical and thermal compatibility, its transport characteristics were 2–5 times worse. Although, PrNi0.4Co0.6O3–δ and PrNi0.4Fe0.6O3–δ represent some disadvantages, this work provides a promising pathway for further improvement of Ni-based perovskite electrodes.