Effects of oxygen content on the oxidation process of Si-containing steel during anisothermal heating

• Published in: International journal of minerals, metallurgy and materials Vol. 25; no. 2; pp. 164 - 172
• Main Authors: Yuan, Qing, Xu, Guang, Liang, Wei-cheng, He, Bei, Zhou, Ming-xing
• Format: Journal Article
• Language: English
• Published: Beijing University of Science and Technology Beijing 01.02.2018; Springer Nature B.V; The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China; Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan 430081, China
• Subjects: Ceramics; Characterization and Evaluation of Materials; Chemistry and Materials Science; Composites; Corrosion and Coatings; Furnaces; Gas mixtures; Glass; Heating; Heating furnaces; High temperature; Materials Science; Metallic Materials; Natural Materials; Oxidation; Oxidation process; Oxidation rate; Oxygen; Oxygen content; Steel; Surfaces and Interfaces; Thin Films; Tribology; 氧化过程;加热过程;Si;气体混合物;钢;线性关系;线性回归方程;氧化行为; oxidation; fayalite; oxidation rate; Si-containing steel; oxygen content; anisothermal heating
• ISSN: 1674-4799; 1869-103X
• DOI: 10.1007/s12613-018-1559-x

The oxidizing behavior of Si-containing steel was investigated in an O2 and N2 binary-component gas with oxygen contents ranging between 0.5 vol% and 4.0 vol% under anisothermal-oxidation conditions. A simultaneous thermal analyzer was employed to simulate the heating process of Si-containing steel in industrial reheating furnaces. The oxidation gas mixtures were introduced from the commencement of heating. The results show that the oxidizing rate remains constant in the isothermal holding process at high temperatures; therefore, the mass change versus time presents a linear law. A linear relation also exists between the oxidizing rate and the oxygen content. Using the linear regression equation, the oxidation rate at different oxygen contents can be predicted. In addition, the relationship between the total mass gain and the oxygen content is linear; thus, the total mass gain at oxygen contents between 0.5 vol%–4.0 vol% can be determined. These results enrich the theoretical studies of the oxidation process in Si-containing steels.