Low-temperature solid-oxide fuel cells utilizing thin bilayer electrolytes

Solid-oxide fuel cells (SOFCs) with electrolytes that provide high open-circuit voltage (OCV) and low ohmic loss down to 550 C are described. The electrolytes were bilayers consisting of a 4 to 8 micron thick Y-doped ceria (YDC) layer with a 1 to 1.5 micron thick Y-doped zirconia (YSZ) layer on the...

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Bibliographic Details
Published inJournal of the Electrochemical Society Vol. 144; no. 5; pp. L130 - L132
Main Authors TSAI, T, PERRY, E, BARNETT, S
Format Journal Article
LanguageEnglish
Published Pennington, NJ Electrochemical Society 01.05.1997
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Summary:Solid-oxide fuel cells (SOFCs) with electrolytes that provide high open-circuit voltage (OCV) and low ohmic loss down to 550 C are described. The electrolytes were bilayers consisting of a 4 to 8 micron thick Y-doped ceria (YDC) layer with a 1 to 1.5 micron thick Y-doped zirconia (YSZ) layer on the fuel side. The cathode/supports were La0.85Sr0.15MnO3-YSZ. The anodes consisted of thin YDC and Ni-YSZ layers. The YDC/YSZ electrolyte SOFCs yielded 85 to 98% of the theoretical OCV, compared with about 50% for YDC electrolyte SOFCs. The cathode overpotential, which was a main factor limiting SOFC power density, was lower for YDC/YSZ than YSZ electrolytes. The maximum power density at 600 C, 210 mW/cm2, is higher than for previously reported SOFCs. 21 refs.
Bibliography:ObjectType-Article-2
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ISSN:0013-4651
1945-7111
DOI:10.1149/1.1837635