A hybrid zeolitic imidazolate framework Co-IM-mIM membrane for gas separation

• Published in: Journal of Central South University Vol. 24; no. 8; pp. 1727 - 1735
• Main Authors: Gao, Zheng-cai, Li, Li-qing, Li, Hai-long, Chen, Ruo-fei, Wang, S., Wang, Yang-gang
• Format: Journal Article
• Language: English
• Published: Changsha Central South University 01.08.2017; Springer Nature B.V
• Subjects: Aluminum oxide; Autoclaving; Carbon dioxide; Dip coatings; Disks; Engineering; Gas permeation; Gas separation; Hydrogen storage; Immersion coating; Metal-organic frameworks; Metallic Materials; Penetration; Pinholes; Polytetrafluoroethylene; Selectivity; secondary growth; separation; Co-IM-mIM membrane; gas permeation
• ISSN: 2095-2899; 2227-5223
• DOI: 10.1007/s11771-017-3580-z

A zeolitic imidazolate hybrid membrane (Co-IM-mIM) containing two imidazolate ligands deposited on a macroporous α-alumina support was prepared by pre-depositing and secondary growth technique. XRD, TGA and SEM characterizations demonstrate that a stable and thin, but dense and pure-phase Co-IM-mIM membrane can be obtained on the macroporous-alumina discs in Teflon-lined autoclave at 120 °C after pre-depositing by dip-coating at room temperature. No visible cracks, pinholes or other defects were observed on the membrane layer. The gas separation studies of Co-IM-mIM membrane were carried out at 25 °C and 1×10 5 Pa, showing ideal selectivity of 6.95, 5.25, 3.40 for H 2 /CO 2 , H 2 /N 2 and H 2 /CH 4 , respectively, and a permeance of 17.37× 10 −6 mol/(m 2 ·s·Pa) for H 2 . The influence of temperature and trans-membrane pressure on hydrogen separation and permeation was also carried out. The gas permeation and selectivity demonstrate that this membrane may have potential applications for efficient H 2 separation.