Trichloridotris{N-[phen-yl(pyridin-2-yl)-methyl-idene]hydroxyl-amine-κN,N'}samarium(III)

The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl(3)N(6) donor set. The mol-ecular structure is stabilized by three intra-molecular O-H⋯Cl hydrogen bonds.

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Published inActa crystallographica. Section E, Structure reports online Vol. 68; no. Pt 3; pp. m344 - m345
Main Authors Lei, Tao, Chen, Wenqian, Chen, Yanmei, Hu, Bin, Li, Yahong
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 01.03.2012
Subjects
Metal-Organic Papers
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Abstract The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl(3)N(6) donor set. The mol-ecular structure is stabilized by three intra-molecular O-H⋯Cl hydrogen bonds.
AbstractList The Sm III ion in the title compound, [SmCl 3 (C 12 H 10 N 2 O) 3 ], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl 3 N 6 donor set. The mol­ecular structure is stabilized by three intra­molecular O—H⋯Cl hydrogen bonds.
The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl(3)N(6) donor set. The mol-ecular structure is stabilized by three intra-molecular O-H⋯Cl hydrogen bonds.
The SmIII ion in the title compound, [SmCl3(C12H10N2O)3], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl3N6 donor set. The molecular structure is stabilized by three intramolecular O—H...Cl hydrogen bonds.
Author Chen, Yanmei
Li, Yahong
Chen, Wenqian
Lei, Tao
Hu, Bin
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/22412474$$D View this record in MEDLINE/PubMed
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Snippet The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal...
The Sm III ion in the title compound, [SmCl 3 (C 12 H 10 N 2 O) 3 ], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic...
The SmIII ion in the title compound, [SmCl3(C12H10N2O)3], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry...
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Title Trichloridotris{N-[phen-yl(pyridin-2-yl)-methyl-idene]hydroxyl-amine-κN,N'}samarium(III)
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