Trichloridotris{N-[phen-yl(pyridin-2-yl)-methyl-idene]hydroxyl-amine-κN,N'}samarium(III)

The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl(3)N(6) donor set. The mol-ecular structure is stabilized by three intra-molecular O-H⋯Cl hydrogen bonds.

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Bibliographic Details
Published inActa crystallographica. Section E, Structure reports online Vol. 68; no. Pt 3; pp. m344 - m345
Main Authors Lei, Tao, Chen, Wenqian, Chen, Yanmei, Hu, Bin, Li, Yahong
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 01.03.2012
Subjects
Metal-Organic Papers
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Summary:The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl(3)N(6) donor set. The mol-ecular structure is stabilized by three intra-molecular O-H⋯Cl hydrogen bonds.
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ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812008100