In-situ preparation of SiC reinforced Si3N4 ceramics aerogels by foam-gelcasting method

• Published in: Ceramics international Vol. 48; no. 1; pp. 1166 - 1172
• Main Authors: Han, Lei, Li, Xiaojian, Li, Faliang, Zhang, Haijun, Liu, Xueyin, Li, Guangqiang, Jia, Quanli, Zhang, Shaowei
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.01.2022
• Subjects: Catalytic reaction; Foam-gelcasting; Low thermal conductivity; SiC reinforced Si3N4 ceramics aerogels; Low thermal conductivity; Catalytic reaction; SiC reinforced Si3N4 ceramics aerogels; Foam-gelcasting
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2021.09.201

High strength SiC reinforced Si3N4 ceramics aerogels (SCSNCAs) were fabricated via foam-gelcasting and subsequent catalytic reaction, utilizing industrial Si and melamine as raw materials, a small amount of incidental Fe impurities in Si powder as the catalyst and cetyltrimethylammonium bromide (CTAB, the amount of 0.075 wt%) as foaming agent. The effects of solid loading level and reaction temperature on phase composition, microstructure and mechanical properties of the as-prepared SCSNCAs were examined. The aerogels prepared at 1423 K using a slurry of solid loading level of 30 wt% (Si:melamine = 3:1, mass ratio) had porosity of 91.9%, having compressive and specific strength of 0.8 MPa and 3.8 MPa·cm3·g−1 exhibited the lowest thermal conductivity of 0.066 W/(m·K) at 473 K. Compared with the control sample (without melamine, i.e., Si3N4 aerogels without the formation of SiC), the specific strength of the SCSNCAs increased by about 10%, which was attributed to the additional reinforcement from SiC whiskers formed in the Si3N4 matrix of the aerogels.