Magnetic Field Effect on the Fluorescence of m-Phenylenebis(phenylmethylene) in a Rigid Glass at 77 K

The magnetic field effect (≤ 0.59 T) on the quintet–quintet fluorescence of m-phenylenebis(phenylmethylene) (MPBP) was studied in a rigid glass, decaline–cyclohexane (3 : 1) mixture, at 77K. The fluorescence decay rate of MPBP increases in a magnetic field. The effect on the MPBP fluorescence is exp...

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Published inBulletin of the Chemical Society of Japan Vol. 74; no. 12; pp. 2325 - 2326
Main Authors Tanimoto, Yoshifumi, Akimoto, Yukimi, Fujiwara, Yoshihisa, Mukai, Masahiro, Takui, Takeji, Kinoshita, Takamasa, Itoh, Koichi
Format Journal Article
LanguageEnglish
Published Tokyo The Chemical Society of Japan 01.12.2001
Chemical Society of Japan
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Summary:The magnetic field effect (≤ 0.59 T) on the quintet–quintet fluorescence of m-phenylenebis(phenylmethylene) (MPBP) was studied in a rigid glass, decaline–cyclohexane (3 : 1) mixture, at 77K. The fluorescence decay rate of MPBP increases in a magnetic field. The effect on the MPBP fluorescence is explained in terms of the Zeeman mixing of excited quintet sublevels of MPBP.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.74.2325