Thermally induced and photoinduced mechanical effects in molecular single crystals-a revival

• Published in: CrystEngComm Vol. 16; no. 1; pp. 185 - 1858
• Main Authors: Nath, Naba K, Panda, Manas K, Sahoo, Subash Chandra, Naumov, Pan e
• Format: Journal Article
• Language: English
• Published: 01.01.2014
• Subjects: Communities; Crystal structure; Crystals; Mathematical analysis; Perception; Perturbation methods; Recognition; Single crystals
• ISSN: 1466-8033; 1466-8033
• DOI: 10.1039/c3ce41313f

The classical perception of single crystals of molecular materials as rigid and brittle entities has downsized the research interest in their mechanical effects that had been initiated and was active back in the 1980s. More recently, the modern analytical techniques for their mechanical, electron-microscopic, structural, spectroscopic and kinematic characterization have contributed to accumulate compelling evidence that under certain circumstances, even some seemingly rigid single crystals can deform, bend, twist, hop, wiggle or perform other 'acrobatics' that are atypical for non-soft matter. These examples contribute to a paradigm shift in our understanding of the elasticity of molecular crystals and also provide direct mechanistic insight into the structural perturbations at the limits of the susceptibility of ordered matter to internal and external mechanical forces. As the relevance of motility and reshaping of molecular crystals is being recognized by the crystal research community as a demonstration of a very basic concept-conversion of thermal or light energy into work-a new and exciting crystal chemistry around mechanically responsive single crystals rapidly unfolds. Mechanically responsive crystals that can be actuated by light or heat, or upon action of mechanical force could be utilized as molecular technomimetic and biomimetic materials. A set of favorable properties, including fast energy transport and favorable elastic properties are promising assets of these materials for rapid actuation at the macroscale.