Structure modulation of two-dimensional transition metal chalcogenides: recent advances in methodology, mechanism and applications

Together with the development of two-dimensional (2D) materials, transition metal dichalcogenides (TMDs) have become one of the most popular series of model materials for fundamental sciences and practical applications. Due to the ever-growing requirements of customization and multi-function, dozens...

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Published inChemical Society reviews Vol. 52; no. 4; pp. 1215 - 1272
Main Authors Xiao, Yao, Xiong, Chengyi, Chen, Miao-Miao, Wang, Shengfu, Fu, Lei, Zhang, Xiuhua
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 20.02.2023
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Summary:Together with the development of two-dimensional (2D) materials, transition metal dichalcogenides (TMDs) have become one of the most popular series of model materials for fundamental sciences and practical applications. Due to the ever-growing requirements of customization and multi-function, dozens of modulated structures have been introduced in TMDs. In this review, we present a systematic and comprehensive overview of the structure modulation of TMDs, including point, linear and out-of-plane structures, following and updating the conventional classification for silicon and related bulk semiconductors. In particular, we focus on the structural characteristics of modulated TMD structures and analyse the corresponding root causes. We also summarize the recent progress in modulating methods, mechanisms, properties and applications based on modulated TMD structures. Finally, we demonstrate challenges and prospects in the structure modulation of TMDs and forecast potential directions about what and how breakthroughs can be achieved. This review provides a comprehensive overview of recent advances in the structure modulation of 2D transition metal chalcogenides, covering structure characteristics, methodology, mechanisms, applications, corresponding challenges and prospects.
Bibliography:Yao Xiao is a Postdoctoral Researcher in the College of Chemistry and Chemical Engineering of Hubei University. He received his PhD from the Institute for Advanced Studies (IAS) of Wuhan University in 2021. During that period, he devoted himself to the structural modulation and theoretical mechanism of 2D TMDs and vertical heterostructures. His current research interests include the synthesis, structure modulation and applications of 2D materials.
Miao-Miao Chen is an Associate Professor in the College of Chemistry and Chemical Engineering, Hubei University. She received her PhD from the College of Chemistry and Molecular Sciences of Wuhan University in 2019. Her current research program aims to design, synthesize, and obtain materials with multifunctional properties for potential applicability as portable electrochemiluminescence sensors.
Shengfu Wang is a Professor in the College of Chemistry and Chemical Engineering, Hubei University. He obtained his MS Degree and PhD from the College of Chemistry and Molecular Sciences of Wuhan University. His recent research interest mainly focuses on the application of functional nanomaterials in electrochemistry and analytical chemistry.
Xiuhua Zhang is a Professor in the College of Chemistry and Chemical Engineering, Hubei University. He received his PhD in the School of Materials Science and Engineering at Hubei University in 2008. Currently, his main interest is developing photoelectric functional materials and their application in electrochemical biosensors.
Chengyi Xiong received his BS Degree from Hubei University in 2013. Subsequently, he obtained his PhD from the College of Chemistry and Chemical Engineering at Southwest University in 2018. Currently, he works as an Assistant Professor at Hubei University. His current research is focused on the synthesis and functionalization of novel luminescent materials, and electrochemiluminescence biosensing and bioimaging.
Lei Fu received his BS Degree in Chemistry from Wuhan University in 2001. He obtained his PhD from the Institute of Chemistry, Chinese Academy of Sciences in 2006. After obtaining his PhD, he worked as a Director's Postdoctoral Fellow at the Los Alamos National Laboratory, Los Alamos, NM (2006-2007). Thereafter, he became an Associate Professor at Peking University. In 2012, he joined Wuhan University as a Full Professor. His current research interests are related to the controlled growth and novel property exploration of 2D atomic layer thin crystals.
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ISSN:0306-0012
1460-4744
DOI:10.1039/d1cs01016f