A water-stable La-MOF with high fluorescence sensing and supercapacitive performances

• Published in: Analyst (London) Vol. 144; no. 15; pp. 4534 - 4544
• Main Authors: Liu, Qian-Qian, Zhang, Shi-Hui, Yang, Jing, Yue, Ke-Fen
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 07.08.2019
• Subjects: Capacitance; Coordination polymers; Crystals; Cycles; Electrode materials; Fluorescence; Gravimetric analysis; Infrared spectroscopy; Metal-organic frameworks; Organic chemistry; Oxygen atoms; Photoelectrons; Recyclability; Single crystals; Spectrum analysis; Stability analysis; Titration; Water stability; X ray photoelectron spectroscopy; X ray powder diffraction; X-ray diffraction
• ISSN: 0003-2654; 1364-5528; 1364-5528
• DOI: 10.1039/c9an00858f

A 3D lanthanide coordination polymer {[La(SIP)(H 2 O) 3 ]·H 2 O} n ( La-MOF ) was synthesized successfully by the solvothermal reaction of La(NO 3 ) 3 ·6H 2 O and 5-sulfoisophthalic acid monosodium salt (NaH 2 SIP). In particular, two oxygen atoms of sulfate participate in the coordination, which is unusual in all the complexes. La-MOF was characterized by single-crystal X-ray diffraction, IR spectroscopy, powder X-ray diffraction, thermal-gravimetric analysis, and X-ray photoelectron spectroscopy. La-MOF shows excellent water stability and chemical stability in a broad pH range from 2 to 13. Moreover, the fluorescence and sensing properties of La-MOF were invsetigated in detail via its titration and cycling processes, revealing its highly efficient and selective quenching responses and good recyclability for the detection of Fe 3+ , Cr 2 O 7 2− and CrO 4 2− ions. In addition, La-MOF possesses an outstanding specific capacitance of 213 F g −1 at 0.5 A g −1 . It still retains 92% of the original capacitance after 2000 cycles, exhibiting remarkable long-term cycling stability and reversibility; therefore, the electrode material based on La-MOF is a competitive and promising candidate for application in supercapacitors. La-MOF shows excellent chemical stability and high fluorescence sensing. La-MOF electrode exhibits high specific capacity and good cycling stability.