Recent progress in organic sensitizers for dye-sensitized solar cells

Dye-sensitized solar cells (DSSCs) are fabricated using low-cost materials and a simple fabrication process; these advantages make them attractive candidates for research on next generation solar cells. In this type of solar cell, dye-sensitized metal oxide electrodes play an important role for achi...

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Published inRSC advances Vol. 5; no. 3; pp. 2381 - 23825
Main Authors Lee, Chuan-Pei, Lin, Ryan Yeh-Yung, Lin, Lu-Yin, Li, Chun-Ting, Chu, Te-Chun, Sun, Shih-Sheng, Lin, Jiann T, Ho, Kuo-Chuan
Format Journal Article
LanguageEnglish
Published 01.01.2015
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Summary:Dye-sensitized solar cells (DSSCs) are fabricated using low-cost materials and a simple fabrication process; these advantages make them attractive candidates for research on next generation solar cells. In this type of solar cell, dye-sensitized metal oxide electrodes play an important role for achieving high performance since the porous metal oxide films provide large specific surface area for dye loading and the dye molecule possesses broad absorption covering the visible region or even part of the near-infrared (NIR). Recently, metal-free sensitizers have made great progress and become the most potential alternatives. This review mainly focuses on recent progress in metal-free sensitizers for applications in DSSCs. Besides, we also briefly report DSSCs with near-infrared (NIR) organic sensitizers, which provide the possibility to extend the absorption threshold of the sensitizers in the NIR region. Finally, special consideration has been paid to panchromatic engineering, co-sensitization, a key technique to achieve whole light absorption for improving the performance of DSSCs. This review focuses on recent progress of metal-free sensitizers and on panchromatic engineering of co-sensitization in dye-sensitized solar cells (DSSCs).
Bibliography:Kuo-Chuan Ho received his BS and MS degrees in the Department of Chemical Engineering of National Cheng Kung University, Taiwan in 1978 and 1980, respectively. He received his PhD in Chemical Engineering at the University of Rochester, USA in 1986. Currently he is a Distinguished Professor jointly appointed by the Department of Chemical Engineering and the Institute of Polymer Science and Engineering at National Taiwan University. His research interests mainly surround applications of chemically modified electrodes to sensing and electro-optical devices, including dye-sensitized solar cells and electrochromic devices.
Chuan-Pei Lee received his PhD degree in Chemical Engineering at National Taiwan University in 2012. Currently, he is a post-doctoral research fellow in the Center for Condensed Matter Sciences at National Taiwan University. His research interests include solar energy and electrochemical energy materials/systems. Besides, he is also familiar with electrochemical analysis and microemulsion synthesis techniques.
Jiann T. Lin received his BS degree in Chemistry from the National Tsing Hua University in 1975. He completed his PhD degree in the Chemistry Department of the University of Minnesota in 1984. After a year as a postdoctoral fellow in the Chemistry Department of the University of Michigan, he joined the Institute of Chemistry, Academia Sinica as a Research Fellow. He was a visiting scholar in Northwestern University in 1991. He is also Adjunct Professor of the National Central University. His current scientific interests involve the study of organic materials for organic light-emitting diodes, organic solar cells and two photon absorption dyes.
Shih-Sheng Sun completed his PhD (2001) in Supramolecular Chemistry at the State University of New York at Binghamton with Prof. Alistair J. Lees. After two-year postdoctoral studies at Northwestern University with Prof. Joseph T. Hupp and Prof. SonBinh T. Nguyen, he joined the Institute of Chemistry, Academia Sinica as an Assistant Research Fellow in 2003 and was promoted to Associated Research Fellow and Research Fellow in 2009 and 2014, respectively. His research interests focus on supramolecular materials chemistry and applications in optoelectronic materials.
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ISSN:2046-2069
2046-2069
DOI:10.1039/c4ra16493h