Similarity and Chirality Measures for Liquid Crystal

The mechanism for the transfer of chirality between a chiral dopant and an achiral liquid crystal host phase remains the subject of conjecture. A review of the theoretical approaches undertaken to create a better understanding of the concept of chirality in liquid crystals proposed a Hausdorff measu...

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Bibliographic Details
Published inMolecular crystals and liquid crystals (Philadelphia, Pa. : 2003) Vol. 494; no. 1; pp. 252 - 257
Main Author Neal, Maureen P.
Format Journal Article
LanguageEnglish
Published Taylor & Francis Group 02.12.2008
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Summary:The mechanism for the transfer of chirality between a chiral dopant and an achiral liquid crystal host phase remains the subject of conjecture. A review of the theoretical approaches undertaken to create a better understanding of the concept of chirality in liquid crystals proposed a Hausdorff measure of chirality between two enantiomers. We compare this measure with a scaled chiral index. The latter has been successful in predicting the helical twisting power of a range of dopants in nematic solvents but possesses no solvent interaction. We propose a combined measure as a predictive tool for helical twisting power and the for the mechanism for chirality transfer.
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ISSN:1542-1406
1563-5287
1543-5318
DOI:10.1080/15421400802430455