Similarity and Chirality Measures for Liquid Crystal
The mechanism for the transfer of chirality between a chiral dopant and an achiral liquid crystal host phase remains the subject of conjecture. A review of the theoretical approaches undertaken to create a better understanding of the concept of chirality in liquid crystals proposed a Hausdorff measu...
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Published in | Molecular crystals and liquid crystals (Philadelphia, Pa. : 2003) Vol. 494; no. 1; pp. 252 - 257 |
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Main Author | |
Format | Journal Article |
Language | English |
Published |
Taylor & Francis Group
02.12.2008
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Subjects | |
Online Access | Get full text |
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Summary: | The mechanism for the transfer of chirality between a chiral dopant and an achiral liquid crystal host phase remains the subject of conjecture. A review of the theoretical approaches undertaken to create a better understanding of the concept of chirality in liquid crystals proposed a Hausdorff measure of chirality between two enantiomers. We compare this measure with a scaled chiral index. The latter has been successful in predicting the helical twisting power of a range of dopants in nematic solvents but possesses no solvent interaction. We propose a combined measure as a predictive tool for helical twisting power and the for the mechanism for chirality transfer. |
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Bibliography: | SourceType-Scholarly Journals-2 ObjectType-Feature-2 ObjectType-Conference Paper-1 content type line 23 SourceType-Conference Papers & Proceedings-1 ObjectType-Article-3 |
ISSN: | 1542-1406 1563-5287 1543-5318 |
DOI: | 10.1080/15421400802430455 |