A comparative study on electromagnetic interference shielding effectiveness of carbon nanofiber and nanofibrillated cellulose composites

• Published in: Synthetic metals Vol. 247; pp. 285 - 297
• Main Authors: Anju, V. P., Manoj, M., Mohanan, Pezholil, Narayanankutty, Sunil K.
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 01.01.2019; Elsevier BV
• Subjects: Absorptivity; Carbon fibers; Carbonaceous materials; Cellulose; Comparative studies; Composite materials; Composites; Electrical resistivity; Electromagnetic shielding; EMI shielding; Flexible thin film; Frequency ranges; High permittivity; Nanofibers; Permittivity; Polyvinyl alcohol; Superhigh frequencies; Thin films; High permittivity; Composites; Flexible thin film; EMI shielding
• ISSN: 0379-6779; 1879-3290
• DOI: 10.1016/j.synthmet.2018.12.021

[Display omitted] •Lightweight, flexible and foldable films of polyvinyl alcohol and polyaniline modified carbon nanofibers were prepared by solvent casting method.•The reported film exhibits high shielding efficiency in both S and X-band frequencies at a thickness of 0.11 mm thickness.•High specific EMI SE of -177 dB cm3/g was obtained for PANI/CNF/PVA composite which is more than the values reported for carbon-based composites.•The flexible composite films of carbon nanofibers exhibited a dielectric constant of 62 and very shallow skin depth of 0.05 at 10.97 GHz.•Easily foldable polymer composite film with excellent absorption dominated electromagnetic interference shielding can be an excellent EMI shielding material. Here we report the microwave characterization and electromagnetic interference (EMI) shielding property of polyvinyl alcohol (PVA) based thin and flexible composite films containing carbon nanofibers (CNF) and nanofibrillated cellulose (NFC). Microwave properties of the composites were analyzed in terms of permittivity, loss tangent, skin depth and absorption coefficient. High permittivity, absorption coefficient and low skin depth were obtained for carbon nanofiber-based composites owing to its good electrical conductivity. The shielding effectiveness (SE) of two composites was measured in the 2–4 GHz (S- band) and 8–12 GHz (X-band) frequency range. Abrupt increase of SE with increasing fiber concentration was observed for CNF based composite. An electromagnetic shielding effectiveness of about −31.5 dB in the S band and of -33.6 dB in the X band was achieved at 0.11 mm thickness. The SE due to absorption (SEA) and reflection (SER) were increased with increase of PANI/CNF content. Additionally, CNF based composite film had a very low density of 0.11 g/cm3. Compared to metals and other carbonaceous materials, this composite film exhibited a high specific EMI shielding efficiency of −177 dB cm3/g.