In situ electrochemical oxidation of ethylenediamine on Co–B alloy electrode during cycling for improving its electrochemical properties at elevated temperature

• Published in: Electrochimica acta Vol. 56; no. 12; pp. 4540 - 4543
• Main Authors: Lu, D.S., Li, W.S., Tan, C.L., Huang, Q.M.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 30.04.2011; Elsevier
• Subjects: Alloy development; Alloy systems; Applied sciences; Cobalt base alloys; Cobalt-boron alloy electrode; Cyclability; Direct energy conversion and energy accumulation; Discharge; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical co-oxidation; Electrochemical conversion: primary and secondary batteries, fuel cells; Electrodes; Electrolytes; Elevated temperature; Ethylenediamine; Exact sciences and technology; High temperature; Oxidation; Ethylenediamine; Elevated temperature; Cyclability; Electrochemical co-oxidation; Cobalt-boron alloy electrode; Fourier transformation; In situ; Alkaline storage battery; Temperature effect; Inductive coupling plasma spectrometry; Electrodes; Emission spectrometry; Cobalt alloy; Reaction mechanism; Oxidation; Carbon monoxide; Electrochemical reaction; Binary alloy; Electrical characteristic; Optical spectrometry; Cycling; Secondary cell; Boron alloys; Discharge; Operating conditions; Infrared spectrometry; Electrode life; Specific capacity
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2011.02.070

► Co–B/ethylenediamine(EDA) hybrid electrode exhibits excellent electrochemical properties. ► The electrochemical oxidation of metallic Co can induce co-oxidation of EDA. ► The oxidation products of EDA may suppress the dissolution of Co in the electrolyte. A Co–B alloy/ethylenediamine (EDA) hybrid electrode system has been developed by adding EDA into electrolyte. Charge–discharge measurements show that the inorganic–organic hybrid electrode system exhibits high discharge capacity and long cycle life at elevated temperature (55 °C). Specifically, in the electrolyte containing 0.09 M EDA additive, the discharge capacity of Co–B alloy electrode after 100 cycles is still up to 601.7 m Ah g −1 at 55 °C. However, for the electrode in EDA-free electrolyte, its discharge capacity is sharply decreased to only 138.5 m Ah g −1 after 100 cycles. ICP-OES and IR measurements are used to clarify the reason of the improvement in the electrochemical properties. These results show that beneficial effect of EDA on electrochemical properties of Co–B alloy electrode can be attributed to in situ electrochemical oxidation of EDA during discharge cycles. First the oxidation of EDA contributes to part of the discharge capacity and secondly the oxidation products absorbed on the electrode may help to suppress the dissolution of Co at elevated temperature. Evidence is presented suggesting that the oxidation of Co can induce co-oxidation of EDA.