Evaluation of lightweight and flexible insulating aerogel blankets based on Resorcinol-Formaldehyde-Silica for space applications

• Published in: European polymer journal Vol. 93; pp. 403 - 416
• Main Authors: Berthon-Fabry, Sandrine, Hildenbrand, Claudia, Ilbizian, Pierre, Jones, Edward, Tavera, Salvatore
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01.08.2017; Elsevier BV; Elsevier
• Subjects: Adsorption; Aerogel; Aerogels; Benzoxazine; Benzoxazines; Bulk density; domain_spi.energ; Engineering Sciences; Formaldehyde; Heat conductivity; Heat transfer; Low density; Low pressure; Materials; Organic-inorganic hybrid; Physical properties; Polymers; Porosity; Silicon dioxide; Space applications; Thermal conductivity; Thermal insulation; Benzoxazine; Low density; Organic-inorganic hybrid; Aerogel; Thermal insulation; Space applications
• ISSN: 0014-3057; 1873-1945
• DOI: 10.1016/j.eurpolymj.2017.06.009

[Display omitted] •Organic-inorganic hybrid aerogel blankets in a one-pot synthesis process.•Insulating lightweight and flexible aerogel blanket for space applications.•Flexible hybrid blanket with ρ=0.04gcm−3 and λ=0.027Wm−1K−1 at RT.•Thermal conductivity of 0.0005Wm−1K−1 in vacuum for encapsulated blanket.•Thermal conductivity of 0.0173Wm−1K−1 at 8mbar He for encapsulated blanket. New hybrid organic-inorganic benzoxazine aerogel blankets for space applications have been synthesized and studied. Aerogel blankets were produced using a one-pot synthesis method with a PET unwoven fibrous network core, resorcinol, formaldehyde and a silica source (APTES with MTES or MTMS as silica co-precursors). Modifying the composition of the sol significantly impacts the physical characteristics of the resulting material such as texture (density and porosity), hydrophilicity, and thermal conductivity. The apparent density of the materials decreases when the percentage of solid in the sol (%solid) decreases and the molar ratio nMTES/nAPTES increases. Within the density range studied, apparent density and effective thermal conductivities are inversely proportional. By replacing a part of APTES by MTES or MTMS the density of the aerogels decreases notably whilst maintaining the level of thermal conductivity. This replacement is detrimental to water adsorption which increases for most conditions studied. When MTMS is used as silica co-precursor instead of MTES no significant differences in water adsorption and thermal conductivity were found. Using the RF-APTES-MTES chemical system we were able to obtain a 3%solid flexible hybrid blanket with both low apparent density (0.04gcm−3) and relatively low effective thermal conductivity (0.027Wm−1K−1 in room conditions). A proof of concept with large panels of this material was done by evaluating them as prototype materials composed of encapsulated aerogel blanket in vacuum and low pressure atmosphere. The blankets show a combination of key characteristics representing the right mix for thermal insulation in space applications operating in non-vacuum environments.