Environmental degradation of materials during wet storage of spent nuclear fuels

• Published in: Journal of materials engineering and performance Vol. 9; no. 3; pp. 317 - 323
• Main Authors: KAIN, Vivekanand, AGARWAL, K, DE, P. K, SEETHARAMAIH, P
• Format: Journal Article
• Language: English
• Published: New York, NY Springer 01.06.2000
• Subjects: Aluminum; Applied sciences; Austenitic stainless steels; Cladding; Corrosion; Corrosion environments; Cracks; Degradation; Exact sciences and technology; Localized corrosion; Metals. Metallurgy; Pools; Spent fuels; Spent nuclear fuels; Zirconium base alloys; Austenitic stainless steel; Radioactive waste; Aluminium base alloys; Electrochemical corrosion; Waste storage; Crevice corrosion; Steel; Experimental study; Waste disposal; Degradation; Pitting corrosion; Wet process; Stainless steel-304; Zircaloy; Combustible waste; Waste-rock interactions; Zirconium base alloys; Environmental protection
• ISSN: 1059-9495; 1544-1024
• DOI: 10.1361/105994900770345980

Wet storage is the predominant mode of storage of spent nuclear fuels. Due to legislation and other constraints, many countries do not reprocess spent fuels and have to store these for extended periods in spent fuel storage pools (SFSPs). Although the water chemistry of the pool is benign, certain factors such as stagnancy of water, crevices, and galvanic contacts between various materials of the fuel clad and the lining of the pools can result in unexpected localized corrosion. In this study, the susceptibility to localized corrosion of aluminum-1S (Al-1S), Zircaloy-2, and type 304 stainless steel (SS) has been assessed using accelerated tests with crevice bent beam (CBB) assemblies. The pool water constituents have been analyzed and electrochemical potentials (ECPs) measured in water samples drawn from different locations of the pool. The ECP has also been measured in situ, in the pools. It has been demonstrated that under conditions of crevice and galvanic contact, aluminum clad fuels from research reactors are prone to localized corrosion even in the benign environments of a SFSP. The ECP experiments indicate the importance of surface condition of the material and irradiation on degradation of various materials due to corrosion.