Preparation of sludge–cyanobacteria composite carbon for synergistically enhanced co-removal of Cu(II) and Cr(VI)

• Published in: Chemosphere (Oxford) Vol. 320; p. 138043
• Main Authors: Li, Lixin, Lv, Ying, Jia, Chao, Yin, Dawei, Dong, Zilong, Zhan, Zhaoshun, Han, Jiazhen, Zhang, Jun
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 01.04.2023
• Subjects: Adsorption; Binary system; Carbon; Chromium - chemistry; Cyanobacteria; Hydrogen-Ion Concentration; Kinetics; Metals, Heavy; Pore structure; Sewage; Sludge; Synergistic adsorption; Water Pollutants, Chemical - analysis; Synergistic adsorption; Sludge; Pore structure; Binary system; Cyanobacteria
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2023.138043

Traditional sludge disposal is currently restricted by the risk of secondary pollution. Sludge carbon material has gained widespread attention because of its low cost and environmentally sustainable properties. However, owing to the high ash content and low–energy density of sludge, sludge pyrolysis alone has certain limitations, and the performance of carbon materials needs to be improved. Herein, a sludge–cyanobacteria composite carbon (SCC) was easily synthesized, and the adsorption process of Cu(II) and Cr(VI) by SCC was examined. SCC-700-2-50% exhibited a high SBET (1047.54 m2/g) and developed pore structure rich in functional groups (such as –NH, –OH, and C–O). The combination of pore structure and functional groups improved the adsorption performance of SCC. The adsorption processes exhibited a synergistic effect in a binary system: the qm of Cu(II) and Cr(VI) were 386 mg/g and 341 mg/g, respectively, and the selectivity of Cu(II) adsorption by SCC was greater than Cr(VI). The adsorption process, examined by SEM-EDS, FTIR, and XPS analysis, indicated that Cu(II) as a cationic interface strengthens Cr(VI) adsorption through electrostatic interaction, and the anion Cr(VI) created a valid electrostatic shield against the electrostatic repulsion between H+ and Cu(II), facilitating Cu(II) adsorption. SCC had great reusability: Cu(II) and Cr(VI) adsorption capacity were 90% and 84%, of the initial adsorption capacity, respectively, after six cycles. This study demonstrates the prospect of SCC as a valid adsorbent for multiple heavy metal contaminations removal. [Display omitted] •High-performance SCC was prepared from sludge and cyanobacteria.•SCC exhibited high adsorption capacity and good regenerative abilities.•Cu(II) enhanced Cr(VI) adsorption by electrostatic interaction.•Cr(VI) promoted Cu(II) adsorption through electrostatic shielding.•SCC as an adsorbent is promising for removing of multiple heavy metal contamination.