All-day passive radiative cooling using common salts

• Published in: Materials horizons Vol. 1; no. 12; pp. 5694 - 573
• Main Authors: Reale Batista, Mariana Desireé, Troksa, Alyssa L, Eshelman, Hannah V, Bagge-Hansen, Michael, Roehling, John D
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 27.11.2023; Royal Society of Chemistry (RSC)
• Subjects: Aerogels; Ambient temperature; Caking; Cooling; Electric contacts; Heating rate; Infrared radiation; Panels; Thermal insulation
• ISSN: 2051-6347; 2051-6355
• DOI: 10.1039/d3mh01139a

Radiative cooling materials underperform compared to their theoretical potential due to parasitic heating from contact with ambient air. Solutions to this problem can be expensive or complex to fabricate. Here, a potentially inexpensive, simply fabricated material that improves cooling performance by reducing parasitic heating was created using naturally abundant salts. NaCl and KCl are not typically considered for radiative cooling because of their high hygroscopicity and low mechanical strength; however, these compounds are highly infrared-transparent and can be fabricated into aerogel-like foam structures to provide thermally insulating properties. The salt foams, described herein, scattered (reflected) visible light, transmitted infrared radiation, and provided thermal insulation. They were packaged into mechanical supporting panels to avoid physical disruption and the nanostructure was stabilized to moisture by adding an anti-caking agent. The panels were able to keep an underlying surface below ambient temperature for a full 24 hour cycle and reduced parasitic heating rate by more than half (compared to an uncovered surface). The panels were able to cool a variety of underlying surfaces, even highly absorbing surfaces that are normally well above ambient temperature during the day. This work demonstrates an affordable, easily produced, electricity-free cooling technology with potential to be manufactured for large-scale practical applications. An infrared transparent foam made from inexpensive salts was developed enabling sub-ambient cooling of underlying surfaces for a full 24 hour cycle. This work showcases how non-convetional materials may be used for passive day-time radiative cooling.