Aluminum Removal from Rare Earth Chloride Solution through Regulated Hydrolysis via Electrochemical Method

• Published in: Separations Vol. 11; no. 5; p. 149
• Main Authors: Zhu, Yaoyao, Li, Jian, Xie, Dongyue, Zhang, Hui, Li, Man, Xu, Binfeng, Zhang, Xuxia, Xie, Yangyang, Qi, Tao
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.05.2024
• Subjects: Aluminum; Aluminum oxide; Chemical tests and reagents; Chloride; Chlorides; Current density; Efficiency; electrochemical; Electrodes; Electron microscopes; Energy consumption; Hydrolysis; Hydroxides; Hydroxyl ions; Innovations; Leachates; Methods; Morphology; Power supply; rare earth; Rare earth compounds; Rare earth elements; Reagents; regulated hydrolysis; Separation; Solvent extraction processes; Sulfuric acid; Temperature; China
• ISSN: 2297-8739; 2297-8739
• DOI: 10.3390/separations11050149

Due to the coexistence of Al3+ and RE3+ and their similar properties, the separation of aluminum from rare earths is difficult. In this study, selective precipitation was used to separate aluminum from rare earth chloride solution via electrochemical regulated hydrolysis. By controlling the current density and electrolytic time, the rate of hydroxyl ion production was regulated, and the selective separation of rare earth and aluminum was realized according to the different precipitation sequences. By altering the temperature, current density, pH value, and other parameters, the separation performance of aluminum from rare earth in mixed rare earth chloride systems was systematically investigated. The removal rate of aluminum reached 88.35%, and the loss rate of rare earth was only 5.99% under optimized conditions. Compared with traditional neutralization hydrolysis, the new process showed higher efficiency and lower rare earth loss rate. Furthermore, a kinetic analysis of aluminum precipitation revealed that the reaction adhered to pseudo-first order kinetics. Additionally, the precipitate obtained via separation and filtration was amorphous alumina hydroxide with a small amount of rare earth attached. No reagent was consumed for the new process, which was more efficient and cleaner, providing a new idea for removing aluminum impurities from rare earth solutions.