Bi‐Microporous Metal–Organic Frameworks with Cubane [M4(OH)4] (M=Ni, Co) Clusters and Pore‐Space Partition for Electrocatalytic Methanol Oxidation Reaction

• Published in: Angewandte Chemie International Edition Vol. 58; no. 35; pp. 12185 - 12189
• Main Authors: Wu, Ya‐Pan, Tian, Jun‐Wu, Liu, Shan, Li, Bo, Zhao, Jun, Ma, Lu‐Fang, Li, Dong‐Sheng, Lan, Ya‐Qian, Bu, Xianhui
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 26.08.2019
• Edition: International ed. in English
• Subjects: Catalysts; cluster compounds; Clusters; Cobalt; Cubane; electrocatalysis; Embedding; Metal-organic frameworks; Methanol; methanol oxidation reaction; Nickel; Oxidation; Partitions; cluster compounds; electrocatalysis; metal-organic frameworks; methanol oxidation reaction

Embedding cubane [M4(OH)4] (M=Ni, Co) clusters within the matrix of metal–organic frameworks (MOFs) is a strategy to develop materials with unprecedented synergistic properties. Herein, a new material type based on the pore‐space partition of the cubic primitive minimal‐surface net (MOF‐14‐type) has...