The Effect of Sodium Dodecyl Benzene Sulfonate on Particle Size in Suspension Polymerization of Styrene: A New Investigation

• Published in: Polymer-plastics technology and engineering Vol. 45; no. 1; pp. 109 - 115
• Main Authors: Shaghaghi, S., Mahdavian, A. R.
• Format: Journal Article
• Language: English
• Published: Philadelphia, PA Taylor & Francis Group 01.02.2006; Taylor & Francis
• Subjects: Applied sciences; Bead size; Exact sciences and technology; Organic polymers; Physicochemistry of polymers; Polymerization; Polystyrene; Preparation, kinetics, thermodynamics, mechanism and catalysts; Sodium dodecyl benzene sulfonate (SDBS); Suspension polymerization; Tricalcium phosphate (TCP); Polymerization modifier; Particle size; s Polystyrene; Sodium dodecyl benzene sulfonate (SDBS); Tricalcium phosphate (TCP); Experimental study; Latex; Bead size; Sulfonate; Anionic surfactant; Calcium Phosphates; Free radical polymerization; Concentration effect; Styrene polymer; Kinetics; Suspension polymerization
• ISSN: 0360-2559; 1525-6111
• DOI: 10.1080/03602550500373659

It is well known that inorganic solids can be used for droplet stabilization in suspension polymerization. This work investigates the effect of tricalcium phosphate (TCP) as an inorganic stabilizer and sodium dodecyl benzene sulfonate (SDBS) as a surface active agent for suspension polymerization of styrene. The results show that when large amounts of TCP is used, the amount of SDBS has no effect on particle size. The effect of concentration of SDBS will be very important if a small amount of TCP is used. Scanning electron microscopy analysis shows that TCP is adsorbed on the surface of monomer droplets and also the coalescence factor changes with concentration of SDBS in the solution.