Microwave synthesis of 3D rambutan-like CuO and CuO/reduced graphene oxide modified electrodes for non-enzymatic glucose detection

A novel type of cupric oxide (CuO) particles-reduced graphene oxide (r-GO) modified electrode has been fabricated through a facile, simple and fast microwave method. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET), and X-ray diffraction (XRD)...

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Published inJournal of materials chemistry. B, Materials for biology and medicine Vol. 4; no. 7; pp. 1247 - 1253
Main Authors Zheng, Jianzhong, Zhang, Wuxiang, Lin, Zhongqiu, Wei, Chan, Yang, Weize, Dong, Peihui, Yan, Yaru, Hu, Shirong
Format Journal Article
LanguageEnglish
Published England 21.02.2016
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Abstract A novel type of cupric oxide (CuO) particles-reduced graphene oxide (r-GO) modified electrode has been fabricated through a facile, simple and fast microwave method. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET), and X-ray diffraction (XRD) were employed to characterize the morphologies and structures of the as-prepared samples. The results reveal that the CuO/r-GO composite was a porous 3D rambutan-like microstructure with high surface area. Then the CuO and CuO/r-GO electrodes were constructed for their use as non-enzymatic glucose biosensors owing to their high-performance and sensitivity under alkaline conditions. The proposed biosensor exhibits glucose concentrations in the range from 0.50 μM to 3.75 mM. Besides, chronoamperometry demonstrates a desirable sensitivity of 52.1 μA mM −1 at an applied potential of 0.50 V ( vs. Ag/AgCl), with a detection limit of 0.10 μM (signal/noise = 3). Most importantly, this non-enzymatic glucose biosensor has highly stable characteristics and can be manufactured into a long-term stability electrode for its application in various complicated circumstances. All these results confirm that this CuO/r-GO biosensor is a promising active material with excellent analytical properties for non-enzymatic glucose detection. Illustration of the glucose biosensing mechanism based on CuO/r-GO composites.
AbstractList A novel type of cupric oxide (CuO) particles-reduced graphene oxide (r-GO) modified electrode has been fabricated through a facile, simple and fast microwave method. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET), and X-ray diffraction (XRD) were employed to characterize the morphologies and structures of the as-prepared samples. The results reveal that the CuO/r-GO composite was a porous 3D rambutan-like microstructure with high surface area. Then the CuO and CuO/r-GO electrodes were constructed for their use as non-enzymatic glucose biosensors owing to their high-performance and sensitivity under alkaline conditions. The proposed biosensor exhibits glucose concentrations in the range from 0.50 μM to 3.75 mM. Besides, chronoamperometry demonstrates a desirable sensitivity of 52.1 μA mM-1 at an applied potential of 0.50 V (vs. Ag/AgCl), with a detection limit of 0.10 μM (signal/noise = 3). Most importantly, this non-enzymatic glucose biosensor has highly stable characteristics and can be manufactured into a long-term stability electrode for its application in various complicated circumstances. All these results confirm that this CuO/r-GO biosensor is a promising active material with excellent analytical properties for non-enzymatic glucose detection.A novel type of cupric oxide (CuO) particles-reduced graphene oxide (r-GO) modified electrode has been fabricated through a facile, simple and fast microwave method. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET), and X-ray diffraction (XRD) were employed to characterize the morphologies and structures of the as-prepared samples. The results reveal that the CuO/r-GO composite was a porous 3D rambutan-like microstructure with high surface area. Then the CuO and CuO/r-GO electrodes were constructed for their use as non-enzymatic glucose biosensors owing to their high-performance and sensitivity under alkaline conditions. The proposed biosensor exhibits glucose concentrations in the range from 0.50 μM to 3.75 mM. Besides, chronoamperometry demonstrates a desirable sensitivity of 52.1 μA mM-1 at an applied potential of 0.50 V (vs. Ag/AgCl), with a detection limit of 0.10 μM (signal/noise = 3). Most importantly, this non-enzymatic glucose biosensor has highly stable characteristics and can be manufactured into a long-term stability electrode for its application in various complicated circumstances. All these results confirm that this CuO/r-GO biosensor is a promising active material with excellent analytical properties for non-enzymatic glucose detection.
A novel type of cupric oxide (CuO) particles-reduced graphene oxide (r-GO) modified electrode has been fabricated through a facile, simple and fast microwave method. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET), and X-ray diffraction (XRD) were employed to characterize the morphologies and structures of the as-prepared samples. The results reveal that the CuO/r-GO composite was a porous 3D rambutan-like microstructure with high surface area. Then the CuO and CuO/r-GO electrodes were constructed for their use as non-enzymatic glucose biosensors owing to their high-performance and sensitivity under alkaline conditions. The proposed biosensor exhibits glucose concentrations in the range from 0.50 μM to 3.75 mM. Besides, chronoamperometry demonstrates a desirable sensitivity of 52.1 μA mM −1 at an applied potential of 0.50 V ( vs. Ag/AgCl), with a detection limit of 0.10 μM (signal/noise = 3). Most importantly, this non-enzymatic glucose biosensor has highly stable characteristics and can be manufactured into a long-term stability electrode for its application in various complicated circumstances. All these results confirm that this CuO/r-GO biosensor is a promising active material with excellent analytical properties for non-enzymatic glucose detection. Illustration of the glucose biosensing mechanism based on CuO/r-GO composites.
A novel type of cupric oxide (CuO) particles-reduced graphene oxide (r-GO) modified electrode has been fabricated through a facile, simple and fast microwave method. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET), and X-ray diffraction (XRD) were employed to characterize the morphologies and structures of the as-prepared samples. The results reveal that the CuO/r-GO composite was a porous 3D rambutan-like microstructure with high surface area. Then the CuO and CuO/r-GO electrodes were constructed for their use as non-enzymatic glucose biosensors owing to their high-performance and sensitivity under alkaline conditions. The proposed biosensor exhibits glucose concentrations in the range from 0.50 μM to 3.75 mM. Besides, chronoamperometry demonstrates a desirable sensitivity of 52.1 μA mM at an applied potential of 0.50 V (vs. Ag/AgCl), with a detection limit of 0.10 μM (signal/noise = 3). Most importantly, this non-enzymatic glucose biosensor has highly stable characteristics and can be manufactured into a long-term stability electrode for its application in various complicated circumstances. All these results confirm that this CuO/r-GO biosensor is a promising active material with excellent analytical properties for non-enzymatic glucose detection.
A novel type of cupric oxide (CuO) particles–reduced graphene oxide (r-GO) modified electrode has been fabricated through a facile, simple and fast microwave method. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer–Emmett–Teller (BET), and X-ray diffraction (XRD) were employed to characterize the morphologies and structures of the as-prepared samples. The results reveal that the CuO/r-GO composite was a porous 3D rambutan-like microstructure with high surface area. Then the CuO and CuO/r-GO electrodes were constructed for their use as non-enzymatic glucose biosensors owing to their high-performance and sensitivity under alkaline conditions. The proposed biosensor exhibits glucose concentrations in the range from 0.50 μM to 3.75 mM. Besides, chronoamperometry demonstrates a desirable sensitivity of 52.1 μA mM⁻¹ at an applied potential of 0.50 V (vs. Ag/AgCl), with a detection limit of 0.10 μM (signal/noise = 3). Most importantly, this non-enzymatic glucose biosensor has highly stable characteristics and can be manufactured into a long-term stability electrode for its application in various complicated circumstances. All these results confirm that this CuO/r-GO biosensor is a promising active material with excellent analytical properties for non-enzymatic glucose detection.
A novel type of cupric oxide (CuO) particles–reduced graphene oxide (r-GO) modified electrode has been fabricated through a facile, simple and fast microwave method. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer–Emmett–Teller (BET), and X-ray diffraction (XRD) were employed to characterize the morphologies and structures of the as-prepared samples. The results reveal that the CuO/r-GO composite was a porous 3D rambutan-like microstructure with high surface area. Then the CuO and CuO/r-GO electrodes were constructed for their use as non-enzymatic glucose biosensors owing to their high-performance and sensitivity under alkaline conditions. The proposed biosensor exhibits glucose concentrations in the range from 0.50 μM to 3.75 mM. Besides, chronoamperometry demonstrates a desirable sensitivity of 52.1 μA mM −1 at an applied potential of 0.50 V ( vs. Ag/AgCl), with a detection limit of 0.10 μM (signal/noise = 3). Most importantly, this non-enzymatic glucose biosensor has highly stable characteristics and can be manufactured into a long-term stability electrode for its application in various complicated circumstances. All these results confirm that this CuO/r-GO biosensor is a promising active material with excellent analytical properties for non-enzymatic glucose detection.
A novel type of cupric oxide (CuO) particles-reduced graphene oxide (r-GO) modified electrode has been fabricated through a facile, simple and fast microwave method. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET), and X-ray diffraction (XRD) were employed to characterize the morphologies and structures of the as-prepared samples. The results reveal that the CuO/r-GO composite was a porous 3D rambutan-like microstructure with high surface area. Then the CuO and CuO/r-GO electrodes were constructed for their use as non-enzymatic glucose biosensors owing to their high-performance and sensitivity under alkaline conditions. The proposed biosensor exhibits glucose concentrations in the range from 0.50 mu M to 3.75 mM. Besides, chronoamperometry demonstrates a desirable sensitivity of 52.1 mu A mM super(-1) at an applied potential of 0.50 V (vs.Ag/AgCl), with a detection limit of 0.10 mu M (signal/noise = 3). Most importantly, this non-enzymatic glucose biosensor has highly stable characteristics and can be manufactured into a long-term stability electrode for its application in various complicated circumstances. All these results confirm that this CuO/r-GO biosensor is a promising active material with excellent analytical properties for non-enzymatic glucose detection.
Author Dong, Peihui
Zhang, Wuxiang
Zheng, Jianzhong
Lin, Zhongqiu
Yan, Yaru
Yang, Weize
Wei, Chan
Hu, Shirong
AuthorAffiliation College of Chemistry and Environment
Institute of Functional Nano & Soft Materials (FUNSOM)
Minnan Normal University
Soochow University
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  name: Minnan Normal University
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  surname: Hu
  fullname: Hu, Shirong
BackLink https://www.ncbi.nlm.nih.gov/pubmed/32262980$$D View this record in MEDLINE/PubMed
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Snippet A novel type of cupric oxide (CuO) particles-reduced graphene oxide (r-GO) modified electrode has been fabricated through a facile, simple and fast microwave...
A novel type of cupric oxide (CuO) particles–reduced graphene oxide (r-GO) modified electrode has been fabricated through a facile, simple and fast microwave...
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SubjectTerms Biosensors
COMPOSITES
COPPER OXIDE
CUPRIC OXIDE
Electrodes
Glucose
Graphene
graphene oxide
microstructure
microwave treatment
MICROWAVES
OXIDES
scanning electron microscopy
silver
silver chloride
surface area
Three dimensional
Transmission electron microscopy
X-ray diffraction
Title Microwave synthesis of 3D rambutan-like CuO and CuO/reduced graphene oxide modified electrodes for non-enzymatic glucose detection
URI https://www.ncbi.nlm.nih.gov/pubmed/32262980
https://www.proquest.com/docview/1800479079
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https://www.proquest.com/docview/2387654431
Volume 4
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