A Chromo-fluorogenic Probe for Selective Detection of Picric Acid Alongside Its Recovery by Aliphatic Amines and Construction of Molecular Logic Gates

• Published in: Journal of fluorescence Vol. 35; no. 2; pp. 751 - 767
• Main Authors: Sarkar, Pallobi, Tohora, Najmin, Mahato, Manas, Ahamed, Sabbir, Sultana, Tuhina, Das, Sudhir Kumar
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.02.2025; Springer Nature B.V
• Subjects: Acetonitrile; Aliphatic amines; Analytical Chemistry; Biochemistry; Biological and Medical Physics; Biomedical and Life Sciences; Biomedicine; Biophysics; Biotechnology; Chemical sensors; Chemoreceptors; Fluorescence; Logic circuits; Memory devices; Optical measuring instruments; Spectrophotometry; Trimethylamine; Logic gates; Picric acid; Reversibility; Paper strip; Molecular keypad
• ISSN: 1573-4994; 1053-0509; 1573-4994
• DOI: 10.1007/s10895-023-03555-y

Nitroaromatic compounds are illicit explosive chemicals. For environmental security and homeland safety, selective and sensitive identification of these secondary-class explosives has been a reason for the exhaustive research arena of chemists for about a decade. We introduced a sensitive optical sensor with desalted neutral red ( NR ) dye. After ingressing picric acid (PA) in acetonitrile, the probe becomes non-fluorescent, displaying a colorimetric change from yellow to pink. The quenched phenomena and the changed color were re-established with aliphatic amine, trimethylamine (TEA). The reversibility is produced cyclically, both in fluorimetrically and spectrophotometrically. The detection limit for PA with our probe comes out as 0.639 µM; this value is significantly lower than many chemosensors available in the literature. Also, NR -stained filter paper strips-based test kit analysis has been deployed as a displayable photonic device for in-situ detection of PA. Furthermore, the whole system was conceptualized to produce single input, single output, and double input single output logic gates, which can be applied to digital devices. The chronological input manner as NTP ( NR - TEA-PA) pushed us to configure a molecular keypad lock system, the basis of digital locking devices. The repeatable & reversible detection system exhibits "Write read- Erase-read Write-read' type memory devices.