Ruthenium oxide-coated carbon felt electrode: A highly active anode for microbial fuel cell applications

• Published in: Journal of power sources Vol. 210; pp. 26 - 31
• Main Authors: Lv, Zhisheng, Xie, Daohai, Yue, Xianjun, Feng, Chunhua, Wei, Chaohai
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15.07.2012; Elsevier
• Subjects: Anode modification; Anodes; Applied sciences; Biochemical fuel cells; Carbon; Direct energy conversion and energy accumulation; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Electrodes; Electron transfer; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cells; Microbial fuel cell; Microorganisms; Nanoparticles; Nanostructure; Ruthenium oxide; Nanoparticles; Ruthenium oxide; Microbial fuel cell; Anode modification; Performance evaluation; Power density; Anode; Nanoparticle; Carbon electrode; Electron transfer; Coatings; Carbon felt; Coated material; Cyclic voltammetry; Biochemical fuel cell; Electrodeposition; Comparative study; Electrochemical impedance spectroscopy
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2012.02.109

► We show the first finding that RuO2 represents a favorable anode material of MFCs. ► Incorporation of RuO2 significantly enhances extracellular electron transfer. ► A maximum power density of 3.08Wm−2 was obtained. ► To our knowledge, it represents a high value ever reported for a dual-chamber MFC. Enhancing the anode performance is a critical step for improving the power output of microbial fuel cells (MFCs). This study presents an active anode that involves the use of ruthenium oxide (RuO2)-coated carbon felt electrode for MFC applications. Cathodic electrodeposition was performed to decorate the carbon felt surface with the RuO2 films composed of submicron-/nano-sized particles. Increasing the amount of charge applied for the electrodeposition resulted in the increase in power performance of MFCs that were inoculated either with the pure culture or the mixed microbial consortia. The dual-chamber MFC equipped with the RuO2-coated anode reached the maximum power density of 3.08Wm−2 (normalized to the projected area of anode), increased by 17 times as compared to that obtained with the MFC with the bare anode. Cyclic voltammetry (CV) and electrochemical impedance spectra (EIS) results provided evidence that there was a substantial improvement in electron transfer between the microbes and the anode. The results demonstrate that RuO2 interacts electrochemically with the cells and has ability to facilitate extracellular electron transfer.