Mass spectral studies of some dithioethers and diamine-dithioethers

The mass spectra of bis(phenylthio)methane, 1,2-bis(phenylthio)ethane, 1,3-bis(phenylthio)propane, 1,6-bis(phenylthio)hexane, 1,8-bit(phenylthio)octane, cis-1,2-bis(phenylthio)ethylene, o-phenylenebis(phenylthioether), some methyl-substituted analogues, and some tetradentate diamine-dithioethers are...

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Published inInorganica Chimica Acta Vol. 27; pp. 185 - 189
Main Authors McAuliffe, C.A., McCullough, F.P., Sedgwick, R.D., Levason, W.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1978
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Summary:The mass spectra of bis(phenylthio)methane, 1,2-bis(phenylthio)ethane, 1,3-bis(phenylthio)propane, 1,6-bis(phenylthio)hexane, 1,8-bit(phenylthio)octane, cis-1,2-bis(phenylthio)ethylene, o-phenylenebis(phenylthioether), some methyl-substituted analogues, and some tetradentate diamine-dithioethers are reported. The fragmentation patterns are illustrated and discussed with respect to differences between the ligands and the fragments derived from different ligands. The completely aliphatic ligands exhibit a complex fragmentation of α and β-cleavages with and without hydrogen atom migration. A number of novel sulphur- and nitrogen-containing heterocycles have been detected.
ISSN:0020-1693
1873-3255
DOI:10.1016/S0020-1693(00)87282-5