A new method for characterizing the bounce and charge transfer properties of nanoparticles

• Published in: Journal of aerosol science Vol. 55; pp. 104 - 115
• Main Authors: Kuuluvainen, Heino, Arffman, Anssi, Saukko, Erkka, Virtanen, Annele, Keskinen, Jorma
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01.01.2013; Elsevier
• Subjects: Aerosols; Bouncing; Charge transfer; Chemistry; Colloidal state and disperse state; ELPI; Exact sciences and technology; General and physical chemistry; Impactor; Nanoparticle; Physical and chemical studies. Granulometry. Electrokinetic phenomena; ELPI; Impactor; Bouncing; Charge transfer; Nanoparticle; Measurement; Ose; Cascade impactor; Fitting; Theory; Method; Sodium chloride; Low pressure; Aerosols; Micrometer; Models; Polydispersed particle; Detection; Performance
• ISSN: 0021-8502; 1879-1964
• DOI: 10.1016/j.jaerosci.2012.08.007

Bouncing and charge transfer between a particle and a surface are fundamental phenomena in aerosol physics. In this study, a new method is presented for characterizing these phenomena in the nanometer size range. The method is based on electrical detection of particles and on a new manner to exploit an electrical low pressure impactor (ELPI). By measuring particles with and without the charger, bouncing and charge transfer can be distinguished. To connect the measurement with the existing theoretical knowledge, a new model describing the bouncing and charge transfer behavior in a cascade impactor is presented. The model is linked to measurements through a fitting process which provides theoretical parameters for polydisperse nanoparticles. With this method, the bouncing and charge transfer of nanoparticles can be described by the existing theory of micrometer-sized particles. To demonstrate the performance of the method in practice, measurements were carried out to define the parameters for sodium chloride and levoglucosan particles. ► Bouncing and charge transfer are distinguished with a simple ELPI measurement. ► Current distributions with and without the charger are measured. ► A new model based on the existing theory of micrometer-sized particles. ► A fitting process combines the model with a polydisperse nanoparticle measurement. ► Parameters for bouncing and charge transfer as a result of the fitting.