Crystal structure of chlorotris(tetracarbonylcobalt)tin, ClSn[Co(CO) 4] 3

The molecular structure of the title compound is unequivocally established by X-ray crystallography. The coordination of Co atoms is trigonal-bipyramidal, whereas that of Sn atom being distorted tetrahedral. The mean Sn-Co distance is 2.60 «. The Sn-Cl bond length (2.54 «) is definitely greater than...

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Published inJournal of organometallic chemistry Vol. 27; no. 3; pp. 337 - 339
Main Authors Bir'yukov, B.P., Kukhtenkova, E.A., Struchkov, Yu.T., Anisimov, K.N., Kolobova, N.E., Khandozhko, V.I.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.03.1971
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Summary:The molecular structure of the title compound is unequivocally established by X-ray crystallography. The coordination of Co atoms is trigonal-bipyramidal, whereas that of Sn atom being distorted tetrahedral. The mean Sn-Co distance is 2.60 «. The Sn-Cl bond length (2.54 «) is definitely greater than the sum of covalent radii (2.39 «.)
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(00)82163-4