High power direct methanol fuel cell with a porous carbon nanofiber anode layer

• Published in: Applied energy Vol. 113; pp. 946 - 954
• Main Authors: Zainoodin, A.M., Kamarudin, S.K., Masdar, M.S., Daud, W.R.W., Mohamad, A.B., Sahari, J.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01.01.2014; Elsevier
• Subjects: Anodes; Applied sciences; Carbon nanofiber; Direct methanol fuel cell; Electrode; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cells; Carbon nanofiber; Direct methanol fuel cell; Electrode; High power; Anode; Carbon; Fuel cell; Methanol
• ISSN: 0306-2619; 1872-9118
• DOI: 10.1016/j.apenergy.2013.07.066

•This study demonstrates a novel porous carbon nanofiber anode (PNCF) layer.•PNFC anode layer DMFC presents power density of 23.0mWcm−2.•This unit operates at room temperature and consumes low concentration of methanol. Three anode electrodes containing Pt–Ru Black as a catalyst were fabricated with a porous layer made with different carbon materials: carbon black (CB), carbon nanofiber (CNF) and a combination of both carbon materials (CB+CNF). The carbon-based porous layer was coated onto a carbon cloth with PTFE pre-treatment for delivering hydrophobic properties and applied in direct methanol fuel cells (DMFCs). Characterisation of electrochemical properties for three different anode electrodes was performed with cyclic voltammetry (CV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) at room temperature in a half-cell configuration. The evolution of the surface morphology of diffusion layer and electrodes was characterised by using variable-pressure scanning electron microscopy (VP-SEM). The electrochemical results indicate that electrode with CNF layer showed the highest current densities compared to CB and CB+CNF with the same catalyst loading. VP-SEM measurements show the network formation within the structure, which could facilitate the methanol mass transfer and improve the catalyst efficiency. The electrodes were applied to a single-cell DMFC, and the cell performance was experimentally investigated under passive operating mode and room temperature. A maximum power density of 23.0mWcm−2 at a current density of 88.0mAcm−2 with a 3M dilute methanol solution was achieved. The results show that the electrodes with a CNF layer could improve the performance of DMFC as compared with commercially used CB and prove it’s potentially application in DMFC technology especially for portable power source applications due to several advantages as followings: operating at low concentration of methanol, operating at room temperature, low catalyst loading in anode and cathode, cheaper, less hazardous and no parasitic load.