Regioselective formation of optically active cycloheptatrienes by chiral tethered Buchner reaction

Optically active cycloheptatrienes were prepared by addition of the rhodium carbenoid to polysubstituted phenyl rings connected by a 2,4-pentanediol tether in sufficient regio- and stereoselectivity.

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Bibliographic Details
Published inChemistry letters Vol. 33; no. 4; pp. 404 - 405
Main Authors Sugimura, T, Ohuchi, N, Kagawa, N, Hagiya, K, Okuyama, T
Format Journal Article
LanguageEnglish
Published TOKYO Chemical Soc Japan 01.04.2004
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
2,4-PENTANEDIOL
INSERTION
ASYMMETRIC-SYNTHESIS
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Summary:Optically active cycloheptatrienes were prepared by addition of the rhodium carbenoid to polysubstituted phenyl rings connected by a 2,4-pentanediol tether in sufficient regio- and stereoselectivity.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2004.404