Epitaxial graphene on ruthenium

• Published in: Nature materials Vol. 7; no. 5; pp. 406 - 411
• Main Authors: Sutter, Peter W., Flege, Jan-Ingo, Sutter, Eli A.
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 01.05.2008; Nature Publishing Group
• Subjects: Biomaterials; Carbon; Catalysis; Chemistry and Materials Science; Condensed Matter Physics; Crystallography; Electronics; Materials Science; Metals; Nanotechnology; Optical and Electronic Materials; Quantum theory; Ruthenium; Substrates
• ISSN: 1476-1122; 1476-4660; 1476-4660
• DOI: 10.1038/nmat2166

Graphene has been used to explore the fascinating electronic properties of ideal two-dimensional carbon, and shows great promise for quantum device architectures. The primary method for isolating graphene, micromechanical cleavage of graphite, is difficult to scale up for applications. Epitaxial growth is an attractive alternative, but achieving large graphene domains with uniform thickness remains a challenge, and substrate bonding may strongly affect the electronic properties of epitaxial graphene layers. Here, we show that epitaxy on Ru(0001) produces arrays of macroscopic single-crystalline graphene domains in a controlled, layer-by-layer fashion. Whereas the first graphene layer indeed interacts strongly with the metal substrate, the second layer is almost completely detached, shows weak electronic coupling to the metal, and hence retains the inherent electronic structure of graphene. Our findings demonstrate a route towards rational graphene synthesis on transition-metal templates for applications in electronics, sensing or catalysis. The large-scale production of high-quality graphene layers is one of the main challenges to be overcome for successful application of this material. Epitaxial growth on ruthenium substrate produces homogeneous domains of single- and double-layer graphene on the scale of several tens of micrometres. The electronic properties of the second layer show great potential for applications.