Synthesis of novel enantiomerically pure trianglimine and trianglamine macrocycles

The synthesis of a series trianglimine macrocycles is described using a [3+3] cyclocondensation strategy between a 1,2-diamine and an aromatic dicarboxaldehyde. The novel compounds have been prepared in enantiomerically pure form and their ring sizes range from 30 to 42. Novel substituted trianglimi...

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Published inTetrahedron: asymmetry Vol. 13; no. 2; pp. 123 - 128
Main Authors Kuhnert, Nikolai, Straßnig, Christian, Lopez-Periago, Ana M.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 28.02.2002
Elsevier
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Chemistry, Physical
Physical Sciences
Science & Technology
TRANSITION-METAL COMPLEXES
CALIXARENES
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ISSN0957-4166
1362-511X
DOI10.1016/S0957-4166(02)00065-4

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Summary:The synthesis of a series trianglimine macrocycles is described using a [3+3] cyclocondensation strategy between a 1,2-diamine and an aromatic dicarboxaldehyde. The novel compounds have been prepared in enantiomerically pure form and their ring sizes range from 30 to 42. Novel substituted trianglimines are synthesised using a [3+3] cyclocondensation.
ISSN:0957-4166
1362-511X
DOI:10.1016/S0957-4166(02)00065-4