Dry gas cleaning in coal gasification systems for fuel cells using composite sorbents

• Published in: Powder technology Vol. 180; no. 1; pp. 232 - 238
• Main Authors: Tsukada, Mayumi, Abe, Kouetsu, Yonemochi, Yuichi, Ameyama, Ayu, Kamiya, Hidehiro, Kambara, Shinji, Moritomi, Hiroshi, Uehara, Takashi
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Lausanne Elsevier B.V 01.01.2008; Elsevier
• Subjects: Alkali and heavy metal; Applied sciences; Chemical engineering; Composite sorbent; Desulfurization; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cells; Gel–sol method; Integrated gasification fuel cell (IGFC); Iron oxide; Miscellaneous; Sintering, pelletization, granulation; Solid-solid systems; Desulfurization; Iron oxide; Gel–sol method; Composite sorbent; Integrated gasification fuel cell (IGFC); Alkali and heavy metal; Specific surface area; Hydrogen sulfides; Iron III Chlorides; Cleaning; Modeling; Composite material; Heavy metal; Coal gasification; Sintering; Coal; Surface area; Fuel cell; Gel-sol method
• ISSN: 0032-5910; 1873-328X
• DOI: 10.1016/j.powtec.2007.03.013

Composite sorbents, for the simultaneous removal of sulfur compounds and alkali and heavy metals from coal gasifier products in an integrated gasification fuel cell (IGFC) system, were prepared. Iron oxide and zinc ferrite were selected as desulfurization sorbents and they were synthesized by precipitation from either ferric chloride, ferric nitride, or ferric and zinc nitride solution. In these solutions, fine oxide particles such as kaolinite, sepiolite, and activated clay, which have the capability of alkali and heavy metal absorption, were dispersed. These oxide particles effectively increased the surface area of synthesized iron oxide and zinc ferrite composite particles. In addition, they are expected to avoid the sintering or coking of the sorbents in the desulfurization and regeneration processes. Desulfurization tests were performed in a tube furnace by streaming a model gas containing H 2S. The desulfurization performance improved considerably in the case of composite sorbents with a high specific surface area. The desulfurization capacity and crystalline phases before and after desulfurization depended on the type of the oxide particle. The desulfurization rate of a composite sorbent was characterized accurately by the specific surface area. Iron oxide and zinc ferrite type desulfurization sorbents containing metal-absorbent particles, such as kaolinite, sepiolite and activated clay, were synthesized by a precipitation-ripening method and a precipitation-calcination method and the desulfurization rate to remove H 2S from the 1000 ppm H 2S-2% H2 balance N 2 model gas increased with the specific surface area of the composite sorbent. [Display omitted]