Silylcarbonylation of 1,5-dienes accompanied by acyl radical cyclization

2-(Silylmethyl)cyclopentanones are prepared from 1,5-dienes, carbon monoxide, and tris(trimethylsilyl)silane (TTMSS) under AIBN initiated free radical reaction conditions.

Saved in:
Bibliographic Details
Published inJournal of organometallic chemistry Vol. 548; no. 1; pp. 105 - 107
Main Authors Ryu, Ilhyong, Nagahara, Kiyoto, Kurihara, Akio, Komatsu, Mitsuo, Sonoda, Noboru
Format Journal Article
LanguageEnglish
Published LAUSANNE Elsevier B.V 05.12.1997
Elsevier
Subjects
1,5-Dienes
Carbon monoxide
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Cyclization
Physical Sciences
Radical
Science & Technology
Silicon hydride
Silylcarbonylation
Carbon monoxide
Silicon hydride
Cyclization
Silylcarbonylation
Radical
1,5-Dienes
silylcarbonylation
silicon hydride
radical
carbon monoxide
ALDEHYDES
1,5-dienes
ISONITRILES
CATALYTIC ROUTE
ALKYNES
cyclization
INTRAMOLECULAR SILYLFORMYLATION
IODIDES
STANNYLFORMYLATION
CARBONYLATION
ACETYLENIC BONDS
CARBON-MONOXIDE
Online AccessGet full text

Cover

More Information
Summary:2-(Silylmethyl)cyclopentanones are prepared from 1,5-dienes, carbon monoxide, and tris(trimethylsilyl)silane (TTMSS) under AIBN initiated free radical reaction conditions.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(97)00167-8