Oxygen-oxygenation of cyclohexene catalyzed by manganese(III), iron(III) and cobalt(II) complexes of tetra-tert-butylphthalocyanine in the presence of iso-butyraldehyde

The title reaction was catalyzed by the manganese(III), iron(III), and cobalt(II) complexes of tetra-tert-butylphthalocyanine, but not by the ligand itself and its zinc(II) complex. When the cobalt(II) complex was used as the catalyst, an induction period was observed.

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Bibliographic Details
Published inInorganic chemistry communications Vol. 2; no. 10; pp. 507 - 509
Main Authors Kasuga, Kuninobu, Tsuboi, Kunio, Handa, Makoto, Sugimori, Tamotsu, Sogabe, Kunihisa
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.10.1999
Subjects
Cyclohexene
Induction period
Oxygen-oxygenation
Phthalocyanine
Induction period
Phthalocyanine
Cyclohexene
Oxygen-oxygenation
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Summary:The title reaction was catalyzed by the manganese(III), iron(III), and cobalt(II) complexes of tetra-tert-butylphthalocyanine, but not by the ligand itself and its zinc(II) complex. When the cobalt(II) complex was used as the catalyst, an induction period was observed.
ISSN:1387-7003
1879-0259
DOI:10.1016/S1387-7003(99)00135-5