Luminescent and mechanical enhancement of phosphorescent hydrogel through cyclic insulation of platinum-acetylide crosslinker

An insulated Pt-acetylide complex was incorporated into a polymer network as a crosslinker to afford a phosphorescent gel. Because of the insulation effect, the formed hydrogel exhibited strong phosphorescence and enhanced mechanical properties compared to those of the uninsulated counterpart due to...

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Bibliographic Details
Published inPolymer chemistry Vol. 1; no. 39; pp. 528 - 5284
Main Authors Russell, Go M, Inamori, Daiki, Masai, Hiroshi, Tamaki, Takashi, Terao, Jun
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 21.10.2019
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Summary:An insulated Pt-acetylide complex was incorporated into a polymer network as a crosslinker to afford a phosphorescent gel. Because of the insulation effect, the formed hydrogel exhibited strong phosphorescence and enhanced mechanical properties compared to those of the uninsulated counterpart due to the inhibition of aggregation among the phosphorescent crosslinkers. An insulated Pt-acetylide complex was incorporated into a polymer network as a crosslinker to afford a phosphorescent gel.
Bibliography:Electronic supplementary information (ESI) available. See DOI
10.1039/c9py00700h
ISSN:1759-9954
1759-9962
DOI:10.1039/c9py00700h